known engineering problems would prevent large-scale implementation of CO 2 storage in such aquifers. The greatest remaining need is to ensure storage security. During CO 2 sequestration in deep aquifers, the captured CO 2 is typically injected into a formation at depths of more than 800 m, where pressure and temperature are above the critical point of CO 2 (31.1°C, 7.38 MPa) (Bachu, 2002). Because supercritical fluids are highly mobile, however, the injected CO 2 might flow in the aquifer and CO 2 might leak to the surface. Storage security therefore depends on restricting CO 2 flow in the storage aquifer.Injected CO 2 can be trapped by either physical or geochemical trapping mechanisms. Structural/ stratigraphic, gravitational, and residual gas trapping are physical mechanisms. In structural/stratigraphic trapping injected CO 2 is stored as a gas, liquid, or supercritical August 24, 2012; Accepted March 9, 2013) Basaltic aquifers have the potential to provide secure option for CO 2 sequestration. Because basaltic rocks are widely distributed around the world, their capacity for storage of anthropogenic CO 2 emissions is enormous. In addition, geochemical trapping of CO 2 injected into basaltic aquifers occurs quickly, because basaltic rocks contain many cations that react with CO 2 to form stable carbonate minerals. Two types of large-scale basaltic aquifers may be suitable for sequestering huge amounts of anthropogenic CO 2 : continental flood basalt aquifers and deep-sea basalt aquifers. Here, we assess the potential of these two CO 2 sequestration options from geological, geochemical and social-scientific perspectives.From a geological and geochemical viewpoint, both continental flood basalt and deep-sea basalt aquifers have excellent CO 2 storage potential. In deep-sea basalt aquifers, however, storage of injected CO 2 may be more secure than in continental flood basalt aquifers, because leakage of CO 2 to the atmosphere is minimized by geological, geochemical and physical barriers associated with the deep-sea environment. In addition, from a social-scientific point of view, several current CO 2 injection projects in continental flood basalts have encountered problems due to groundwater depletion, and large-scale implementation of CO 2 storage in continental flood basalt aquifers might cause contamination of freshwater resources needed for domestic and agricultural use. In striking contrast to continental flood basalts, deep-sea basalts can be used for CO 2 storage without encountering critical problems, because deep-sea basalt aquifers have no economic value. We conclude, therefore, that deep-sea basalt aquifers are a better option for CO 2 storage than continental flood basalt aquifers.