Activity concentrations of natural radioactivity of 40 K, 238 U, 226 Ra, and 232 Th were reviewed in connection with rock, soil, sediments, and water in the Northern and Southern parts of Nigeria to estimate the radiation dose acquire by the population. The activity concentrations of the various radionuclides from rock samples collected from different locations were generally higher than those of other environmental matrices. Comparative distribution maps of 40 K, 238 U, and 232 Th show the distribution of activity concentration in the Northern and Western part of Nigeria.