In this study, the activities of 40 K, 210 Pb, 232 Th, 234 U, 235 U, and 238 U in size-segregated particulate matter (PM) were measured in the Singrauli Coalfield, India. Different isotopic compositions were found relative to natural uranium ratios. The radioactivity concentration ratios in different PM sizes [PM 2.5 , PM 10 , and suspended particulate matter (SPM)] suggested that anthropogenic sources affected the uranium isotopic compositions in the area. A different isotopic composition from the natural uranium composition was found. The correlation coefficients between the measured isotopes (40 K, 210 Pb, 232 Th, 234 U, 235 U, and 238 U) and meteorological factors were calculated. PM emissions were affected by the meteorological conditions, which in turn, influenced the U and Th concentrations in PM. The 232 Th/ 238 U activity ratio in particulate matter was between 0.20 and 1.54 with an average value of 0.9 ± 0.5, 0.2 to 1.1 (0.8 ± 0.7), and 0.2 to 1.2 with an average value of 0.8 ± 0.8 in PM 2.5 , PM 10 , and SPM, respectively. These range were quite different from the average crustal ratio of 3.5, indicating that the 238 U concentrations were elevated in this region relative to Th. However, compared with Th, the dose contribution of U to the public was negligible. The average effective dose in public owing to inhalation of natural radioactive 40 K, 210 Pb, 232 Th, and 234 U, 235 U, and 238 U in the atmosphere was between 0.03 and 327 nSv year −1. These doses associated with the inhalation of particulate matter were lower than world airborne reference value as reported by UNSCEAR (2000a).