Natural rubber (Hevea Brasiliensis)-based quasi-solid electrolyte as a potential candidate for arresting recombination and improving performance in aqueous dye-sensitized solar cells

Kamenan, Koffi A.; Jagadeesh, Anooja; Kre, N’guessan Raymond; Assanvo, Edja F.; Soman, Suraj; Unni, K. N. Narayanan

doi:10.1007/s10854-021-05979-3

Cited by 10 publications

(4 citation statements)

References 37 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The optimized aqueous quasi-solid state iodide/triiodide electrolyte based on NR latex produced an improvement of %84% in power conversion efficiency (PCE) under 0.9 (90 mW cm À2 ) condition compared to standard WE. [19] NR can also be modified into epoxy groups, known as the ENR, which can contribute to a good conduction path of carrier ions. It is possible to create a flexible and high ionic conductivity sheet in electrolytes by employing ENR as a polymer.…”

Section: Nr Electrolytesmentioning

confidence: 99%

See 1 more Smart Citation

Exploring the Potential of Natural Rubber as Electrolytes and Electrodes for Advanced Energy Storage Applications

Kamarulazam,

Manogran,

Goh

et al. 2023

Energy Tech

View full text Add to dashboard Cite

Amid the search for alternatives to petrochemical‐based polymers and growing concern for environmental sustainability, natural polymers have gained significant attention. These polymers have potential applications in household appliances to advanced energy systems and offer a way to address the depletion and sustainability challenges associated with synthetic polymers. One such natural source of polymer is natural rubber (NR), which has been developed as a highly performing material in electrodes and electrolytes. Nowadays, researchers are more interested in NR due to its sustainability, affordability, elastomeric properties, and low glass transition temperature. This article presents a comprehensive exploration of NR characteristics, delving into its elasticity, glass transition temperature, and an extensive evaluation of its potential as a hydrogel electrolyte. Furthermore, this investigation showcases NR's capability to mitigate potential long‐term consequences of synthetic materials. Given NR's inherent insulating nature, a meticulous analysis of the interplay between NR composites and their electrical properties within electrodes is prompted. This article provides a review of past research, growth and development, and prospects of NR and its derivatives as in applications including electrochemical energy storage, energy harvesting, wastewater treatment, and slow‐release fertilizers. Moreover, the study briefly underscores the importance of NR while acknowledging its limitations.

show abstract

Section: Nr Electrolytesmentioning

confidence: 99%

“…The optimized aqueous quasi‐solid state iodide/triiodide electrolyte based on NR latex produced an improvement of ≈84% in power conversion efficiency (PCE) under 0.9 (90 mW cm −2 ) condition compared to standard WE. [ 19 ]…”

Section: Nr and Its Derivativesmentioning

confidence: 99%

Exploring the Potential of Natural Rubber as Electrolytes and Electrodes for Advanced Energy Storage Applications

Kamarulazam,

Manogran,

Goh

et al. 2023

Energy Tech

View full text Add to dashboard Cite

show abstract

“…This has prompted research into aqueous-based electrolyte systems, known for their cost-effectiveness, abundant water resources, and improved environmental compatibility. [197][198][199][200][201] The framework of quasi-solid-state or solid-state electrolytes demonstrates relative stability, providing an additional opportunity to customize the light propagation in DSSC research. Zhongze Gu et al [202] achieved an enhanced PCE of 1.8 % which is ca.…”

Section: Aqueous Quasi Solid-state Dye-sensitized Solar Cells (Aq-qss...mentioning

confidence: 99%

“…Nevertheless, the conventional DSSC with organic solvents presents certain limitations such as low boiling points and harmful environmental effects. This has prompted research into aqueous‐based electrolyte systems, known for their cost‐effectiveness, abundant water resources, and improved environmental compatibility [197–201] . The framework of quasi‐solid‐state or solid‐state electrolytes demonstrates relative stability, providing an additional opportunity to customize the light propagation in DSSC research.…”

Section: Aqueous Quasi Solid‐state Dye‐sensitized Solar Cells (Aq‐qss...mentioning

confidence: 99%

Molecular Engineering of Photosensitizers for Solid‐State Dye‐Sensitized Solar Cells: Recent Developments and Perspectives

Yadagiri,

Kumar Kaliamurthy,

Yoo

et al. 2023

ChemistryOpen

View full text Add to dashboard Cite

Dye‐sensitized solar cells (DSSCs) are a feasible alternative to traditional silicon‐based solar cells because of their low cost, eco‐friendliness, flexibility, and acceptable device efficiency. In recent years, solid‐state DSSCs (ss‐DSSCs) have garnered much interest as they can overcome the leakage and evaporation issues of liquid electrolyte systems. However, the poor morphology of solid electrolytes and their interface with photoanodes can minimize the device performance. The photosensitizer/dye is a critical component of ss‐DSSCs and plays a vital role in the device‘s overall performance. In this review, we summarize recent developments and performance of photosensitizers, including mono‐ and co‐sensitization of ruthenium, porphyrin, and metal‐free organic dyes under 1 sun and ambient/artificial light conditions. We also discuss the various requirements that efficient photosensitizers should satisfy and provide an overview of their historical development over the years.

show abstract

Water as Dual‐Function Plasticizer and Cosolvent in Gel Electrolytes for Dye‐Sensitized Solar Cells

Goh,

Farhana,

Kamarulazam

et al. 2024

Macromol. Rapid Commun.

View full text Add to dashboard Cite

This study presents a novel approach to developing eco‐friendly dye‐sensitized solar cells (DSSCs) using natural and renewable materials for gel polymer electrolytes (GPEs), reducing reliance on unsustainable solvents. Water is added to polar aprotic solvents, specifically ethylene carbonate/propylene carbonate (EC/PC), across various mass fractions (0:100 to 100:0). An amphiphilic hydroxypropyl cellulose (HPC) natural polymer is employed to formulate GPEs within this water‐EC/PC cosolvent system, achieving successful gelation up to 50:50 mass fractions. Incorporating water reduced the gel strength and viscosity of the GPEs. Water acted as a plasticizer, enhancing the polymer chains mobility, and creating a more flexible and permeable structure. This increased ion diffusion coefficients and ion mobility, resulting in a maximum ionic conductivity of 18.17 mS cm−1. The highest efficiency achieved in DSSCs using these GPEs is 5.81%, with elevated short‐circuit current density and reduced recombination losses. However, some compositions experienced syneresis, affecting their stability. The GPE with a 40:60 mass fraction exhibited superior long‐term stability because it is free from syneresis, though it achieved a lower efficiency (4.83%), making it the best‐performing sample. This work demonstrates the feasibility and benefits of using gel polymer electrolytes in an aqueous system, improving DSSC efficiency and sustainability.

show abstract

Natural rubber (Hevea Brasiliensis)-based quasi-solid electrolyte as a potential candidate for arresting recombination and improving performance in aqueous dye-sensitized solar cells

Cited by 10 publications

References 37 publications

Exploring the Potential of Natural Rubber as Electrolytes and Electrodes for Advanced Energy Storage Applications

Exploring the Potential of Natural Rubber as Electrolytes and Electrodes for Advanced Energy Storage Applications

Molecular Engineering of Photosensitizers for Solid‐State Dye‐Sensitized Solar Cells: Recent Developments and Perspectives

Water as Dual‐Function Plasticizer and Cosolvent in Gel Electrolytes for Dye‐Sensitized Solar Cells

Contact Info

Product

Resources

About