2014
DOI: 10.1007/s00396-014-3396-4
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Natural rubber with nanomatrix of non-rubber components observed by focused ion beam-scanning electron microscopy

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Cited by 26 publications
(20 citation statements)
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“…Naturally occurring networks derived from non‐rubber components and film formation efficiency are also contributory factors. Non‐rubber components, namely proteins and phospholipids on surface membrane of RPs could act as natural branch points and nanofillers, which become supporting framework in rubber matrix after film‐forming . The natural networks mainly formed by phospholipid linkages of LRP were found to be stronger than that formed by protein interactions of SRP .…”
Section: Resultsmentioning
confidence: 99%
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“…Naturally occurring networks derived from non‐rubber components and film formation efficiency are also contributory factors. Non‐rubber components, namely proteins and phospholipids on surface membrane of RPs could act as natural branch points and nanofillers, which become supporting framework in rubber matrix after film‐forming . The natural networks mainly formed by phospholipid linkages of LRP were found to be stronger than that formed by protein interactions of SRP .…”
Section: Resultsmentioning
confidence: 99%
“…Non-rubber www.advancedsciencenews.com www.mme-journal.de components, namely proteins and phospholipids on surface membrane of RPs could act as natural branch points and nanofillers, which become supporting framework in rubber matrix after film-forming. [47] The natural networks mainly formed by phospholipid linkages of LRP were found to be stronger than that formed by protein interactions of SRP. [8] Moreover, the collapse of the top surface of the RPs in the LRP film facilitates inter-particle diffusion of rubber chains across boundaries of RPs thereby improving film-forming efficiency, while excessive crosslink density within RP in SRP films decreased the packing ability and resisted the integration of latex particles during film formation resulting in unfavorable tensile properties.…”
Section: Tensile Properties Of Pre-vulcanized Rubber Filmsmentioning
confidence: 99%
“…Therefore, the proteins and phospholipids of the particles may merge into each other to form a dispersion medium, when the latex is coagulated. NR may, thus, possess the nanomatrix structure, which consists of NR particles of about 1 µm in diameter as a dispersoid and the nanomatrix of the proteins and phospholipids as a medium. Figure shows transmission electron microscopy (TEM) images for fresh NR, HANR and DPNR, which were stained with phosphotungstic acid.…”
Section: Resultsmentioning
confidence: 99%
“…It is, thus, required to investigate the mechanical properties of the rubbery polymers with respect to the nanomatrix structure. The 3D image of the nanomatrix structure formed by non‐rubber components was observed, in which rubber particles were dispersed in the nanomatrix of non‐rubber components such as proteins and phospholipids, whose thickness was several 10 nm . The outstanding mechanical properties of NR may, perhaps, be associated with the spatial arrangement of the non‐rubber components in the nanomatrix structure.…”
Section: Introductionmentioning
confidence: 99%
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