Naturally Derived Cements Learned from the Wisdom of Ancestors: A Literature Review Based on the Experiences of Ancient China, India and Rome

Abstract

For over a thousand years, many ancient cements have remained durable despite long-term exposure to atmospheric or humid agents. This review paper summarizes technologies of worldwide ancient architectures which have shown remarkable durability that has preserved them over thousands of years of constant erosion. We aim to identify the influence of organic and inorganic additions in altering cement properties and take these lost and forgotten technologies to the production frontline. The types of additions were usually decided based on the local environment and purpose of the structure. The ancient Romans built magnificent structures by making hydraulic cement using volcanic ash. The ancient Chinese introduced sticky rice and other local materials to improve the properties of pure lime cement. A variety of organic and inorganic additions used in traditional lime cement not only changes its properties but also improves its durability for centuries. The benefits they bring to cement may also be useful in enzyme-induced carbonate precipitation (EICP) and microbially induced carbonate precipitation (MICP) fields. For instance, sticky rice has been confirmed to play a crucial role in regulating calcite crystal growth and providing interior hydrophobic conditions, which contribute to improving the strength and durability of EICP‑ and MICP-treated samples in a sustainable way.

INVESTIGATION OF MASS GRADIENT OF CONCRETE FILLED WITH POLYACRYLAMIDE/Fe3O4 MAGNETITE NANOPARTICLES İN CASPIAN SEA AND FORMATION WATER MEDIUM

“…As is known, the concrete is an irreplaceable material used in all areas of modern construction. Historically, cement mixes used volcanic ash, limenit, and seawater, but today engineers also use Portland cement being mixed with aggregates such as gravel and sand [1]. When the concrete comes into contact with certain chemicals such as acids, it reacts with the calcium hydroxide in the cement and forms water-soluble calcium compounds, which are then washed out [2].…”