An interconnected network features a structural transition between two regimes [F. Radicchi and A. Arenas, Nat. Phys. 9, 717 (2013)]: one where the network components are structurally distinguishable and one where the interconnected network functions as a whole. Our exact solution for the coupling threshold uncovers network topologies with unexpected behaviors. Specifically, we show conditions that superdiffusion, introduced by Gómez et al. [Phys. Rev. Lett. 110, 028701 (2013) Fig. 1, where the interconnection strength between the layers is parametrized by a coupling weight p > 0. Radicchi and Arenas [16] demonstrated the existence of a structural transition point p * . Depending on the coupling weight p between the two networks, the collective interconnected network can function in two regimes: if p < p * , the two networks are structurally distinguishable; whereas if p > p * , they behave as a whole.While studying diffusion processes on the same type of interconnected network in Fig. 1, Gomez et al. [14] observed superdiffusion: for sufficiently large p, the diffusion in the interconnected network takes place faster than in either of the networks separately. Superdiffusion arises due to the synergistic effect of the network interconnection and exemplifies a characteristic phenomenon in interconnected networks. Placement of the introduction point of superdiffusion with respect to the critical point p * is missing in the literature.Whereas the existence of a critical transition p * was reported in [16], here, we determine the exact coupling threshold p * . Our exact solution illuminates the role of each individual * Corresponding author: faryad@ksu.edu network component and their combined configuration on the structural transition phenomena and uncovers unexpected behaviors. Specifically, we show structural transition is not a necessary condition for achieving superdiffusion. Indeed, superdiffusion can be achieved for a coupling weight p even below the structural transition threshold p * , which is surprising because, intuitively, synergy is not expected if the network components are functioning distinctly. Moreover, we observe that the structural transition disappears when one of the network components has vanishing algebraic connectivity [18][19][20], as is the case for a class of scalefree networks. Therefore, components of such interconnected network topologies become indistinguishable despite very weak coupling between them.Spectral analysis plays a key role in understanding interconnected networks. Hernandez et al. [21] found the complete spectra of interconnected networks with identical components. studied the interconnection of more than two networks with an arbitrary oneto-one correspondence structure. employed eigenvalue interlacing [18] to provide bounds for the Laplacian spectra of an interconnected network with a general interconnection pattern. In addition, in a similar context of structural transition as [16], D'Agostino [24] showed that adding interconnection links among networks causes st...