Design and performance of a newly developed multi-wavelength, micro Raman spectroscopy system for non-contact and non-destructive characterization of semiconductor materials are introduced. The thickness and Ge content of Si 1-x Ge x /Si were estimated from the multiwavelength Raman measurement results and compared to those values obtained from X-ray diffraction (XRD) and Xray reflectance (XRR) measurements for cross-reference. Both the thickness and Ge content of Si 1-x Ge x /Si measured by Raman spectroscopy and X-ray techniques are in excellent agreement. In addition to the non-contact and nondestructive nature of Raman spectroscopy, the multiwavelength excitation capability of the system, with high spectral and spatial resolution, are very attractive and powerful for characterization of advanced semiconductor materials, such as Si 1-x Ge x /Si and strained Si, and process optimization.978-1-4244-3815-0/09/$25.00 ©IEEE