Variations in injection-current waveform are examined using diplexed RF-modulation with continuous-wave distributed-feedback (CW-DFB) lasers, with the aim to maximize the spectral tuning range and signal-to-noise ratio for MHz-rate laser absorption spectroscopy. Utilizing a bias-tee circuit, laser chirp rates are shown to increase by modulating the AC input voltage using square waves instead of sine waves and by scanning the laser below the lasing threshold during the modulation period. The effect of waveform duty cycle and leading-edge ramp rate are further examined. A spectral scan depth on the order of 1 cm-1 at a scan frequency of 1 MHz is achieved with a representative CW-DFB quantum cascade laser near 5 µm. Distortion of high-frequency optical signals due to detector bandwidth is also examined, and limitations are noted for applications with narrow spectral features and low-bandwidth detectors. Based on common detection system limitations, an optimization approach is established for a given detection bandwidth and target spectra. A representative optimization is presented for measurements of sub-atmospheric carbon monoxide spectra with a 200-MHz detection system. The methods are then demonstrated to resolve transient gas properties (pressure and temperature) via laser absorption spectroscopy at MHz rates in a detonation tube and shock tube facility. An appendix detailing a first-order model of high-speed distributed feedback laser tuning dynamics is also included to support the experimental observations of this work.