1995
DOI: 10.1021/j100038a054
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Near-Infrared Spectroscopic Investigation of Inclusion Complexes between Cyclodextrins and Aromatic Compounds

Abstract: Near infrared (NIR) absorption in the 900-1800 nm region has been used to characterize and measure the association constants of the inclusion complexes between aromatic compounds (e.g., phenol, 4-chlorophenol, sodium 2-naphthalenesulfonate, and sodium 2-pyrenesulfonate) and a-, B-, and y -cyclodextrin. It was found that the NIR method is particularly suited for this type of study because upon forming complexes, the oscillator strengths of the C-H stretching [Av = 2 (at -1650 nm) and 3 (at -1 120 nm)] overtone … Show more

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Cited by 23 publications
(31 citation statements)
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“…Additionally, NIR absorption is known to be sensitive to intermolecular structure and interactions [6]. For example, we successfully used NIR technique to determine binding constants of inclusion complexes between various compounds with cyclodextrins in aqueous solutions as well as in room-temperature ionic liquids [7][8][9]. Transformation of a surfactant solution from pre-micelles to post-micelles should lead to changes in NIR absorption.…”
Section: Introductionmentioning
confidence: 99%
“…Additionally, NIR absorption is known to be sensitive to intermolecular structure and interactions [6]. For example, we successfully used NIR technique to determine binding constants of inclusion complexes between various compounds with cyclodextrins in aqueous solutions as well as in room-temperature ionic liquids [7][8][9]. Transformation of a surfactant solution from pre-micelles to post-micelles should lead to changes in NIR absorption.…”
Section: Introductionmentioning
confidence: 99%
“…Near-infrared (NIR) spectra were taken on a home-built NIR spectrometer (23, 24). FT-IR spectra were measured on a PerkinElmer 100 spectrometer.…”
Section: Methodsmentioning
confidence: 99%
“…The absorption spectra were measured on an AOTF-based near-IR spectrophotometer developed in our laboratory. 6,10…”
Section: B Instrumentationmentioning
confidence: 99%