The problem of water pollution caused by antibiotics
urgently needs
to be solved urgently. In this study, the Bi5O7I:Er3+-Yb3+ (BOIEY) nanoflowers with a diameter
of 600–900 nm loaded flexible fibrous membrane has been synthesized
via a combined hydrothermal and electrospinning process. It is noteworthy
that the composite fibers successfully achieved efficient catalytic
purification under real-time temperature monitoring. The BOIE0.5Y1.5/PAN composite fibers displayed the highest
photocatalytic performance in the degradation of tetracycline hydrochloride
(TC-HCl), with a removal rate of 91.83% in 80 min, which is 1.76 times
that of pure BOI. The efficient photocatalytic performance was mainly
attributed to the doping of rare earth ions and the special structure
of the composite fibers. Er3+ and Yb3+ ions
played the role of broadening the absorption spectrum by upconverting
near-infrared light into visible light and promoted the separation
of electron and hole pairs, thereby improving the photocatalytic efficiency.
In addition, the unique structure of the hollow spherical-flower-loaded
flexible fibrous membrane exhibited a larger specific surface area
and stronger photon absorption capacity compared with traditional
nanocrystals (NCs). Furthermore, based on the 2H11/2/4S3/2 → 4I15/2 radiative transitions of Er3+, the real-time temperature
feedback of the degradation process in the 303–433 K ranges
is evaluated and the relative temperature sensitivity reaches 0.63%
K–1 at 353 K. The dual-function composite fibers
provide insight into antibiotic removal in complex environments and
ecological restoration.