Near Net Shape Manufacturing of Sheets from Al-Cu-Li-Mg-Sc-Zr Alloy

Abstract

Thin twin-roll cast strips from a model Al-Cu-Mg-Li-Zr alloy with a small addition of Sc were prepared. A combination of a fast solidification rate and a favorable effect of Sc microalloying refines the grain size and the size of primary phase particles and reduces eutectic cell dimensions to 10–15 μm. Long-term homogenization annealings used in conventionally cast materials lasting several tens of hours followed by a necessary dimension reduction through rolling/extruding could be substituted by energy and material-saving procedure. It consists of two-step short annealings at 300 °C/30 min and 450 °C/30 min, followed by the refinement and hardening of the structure using constrained groove pressing. A dense dispersion of 10–20 nm spherical Al3(Sc,Zr) precipitates intensively forms during this treatment and effectively stabilizes the structure and inhibits the grain growth during subsequent solution treatment at 530 °C/30 min. Small (3%) pre-straining after quenching assures more uniform precipitation of strengthening Al2Cu (θ′), Al2CuMg (S′), and Al2CuLi (T1) particles during subsequent age-hardening annealing at 180 °C/14 h. The material does not contain a directional and anisotropic structure unavoidable in rolled or extruded sheets. The proposed procedure thus represents a model near net shape processing strategy for manufacturing lightweight high-strength sheets for cryogenic applications in aeronautics.

Optimizing the Heat Treatment Method to Improve the Aging Response of Al-Fe-Ni-Sc-Zr Alloys

“…Nevertheless, Zr shows a superior function [32][33][34]. In the precipitates, Zr can partially replace the Sc position to form an Al 3 (Sc, Zr) core-shell structure [35][36][37][38]. The Sc element is mainly concentrated on the core, and the Zr element is mainly concentrated on the shell [39,40].…”