Annealing of amorphous optical coatings has been shown to generally
reduce optical absorption, optical scattering, and mechanical loss,
with higher temperature annealing giving better results. The
achievable maximum temperatures are limited to the levels at which
coating damage, such as crystallization, cracking, or bubbling, will
occur. Coating damage caused by heating is typically only observed
statically after annealing. An experimental method to dynamically
observe how and over what temperature range such damage occurs during
annealing is desirable as its results could inform manufacturing and
annealing processes to ultimately achieve better coating performance.
We developed a new, to the best of our knowledge, instrument that
features an industrial annealing oven with holes cut into its sides
for viewports to illuminate optical samples and observe their coating
scatter and eventual damage mechanisms in
situ and in real time during annealing. We present results
that demonstrate in situ observation of
changes to titania-doped tantala coatings on fused silica substrates.
We obtain a spatial image (mapping) of the evolution of these changes
during annealing, an advantage over
x
ray diffraction, electron beam, or
Raman methods. We infer, based on other experiments in the literature,
these changes to be due to crystallization. We further discuss the
utility of this apparatus for observing other forms of coating damage
such as cracking and blisters.