2009
DOI: 10.1111/j.1551-2916.2009.03289.x
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Negative Temperature Coefficient Material with Low Thermal Constant and High Resistivity for Low‐Temperature Thermistor Applications

Abstract: The negative temperature coefficient material with low thermal constant B and high resistivity were explored for low‐temperature thermistor applications. The spinel oxide Fe0.5Cu0.2Ni0.66Mn1.64O4 had a required low B value, but its resistivity was much lower than the required value. To increase the resistivity, yttrium‐stabilized zirconia (YSZ) was introduced into the spinel oxide. The spinel oxide in composite with YSZ (80 mol%) exhibited a much increased resistivity (10 479 Ω·cm at 25°C) while without causin… Show more

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Cited by 56 publications
(20 citation statements)
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“…Besides Ni and Mn present in the cubic nickel manganite spinel oxide, different elements such as Cu, Zn, Fe, Co, Mg, Si have been added in varied amounts and combinations while retaining the cubic spinel structure [1,3,8,14,15]. Addition of other metal elements influences the three basic thermistor parameters -25 , B-value and stability in different ways [17][18][19][20][21][22][23][24][25]. These parameters are also strongly influenced by the manufacturing conditions that include the powder preparation procedure and processing conditions such as the sintering temperature, rate of cooling and sintering duration.…”
Section: Introductionmentioning
confidence: 99%
“…Besides Ni and Mn present in the cubic nickel manganite spinel oxide, different elements such as Cu, Zn, Fe, Co, Mg, Si have been added in varied amounts and combinations while retaining the cubic spinel structure [1,3,8,14,15]. Addition of other metal elements influences the three basic thermistor parameters -25 , B-value and stability in different ways [17][18][19][20][21][22][23][24][25]. These parameters are also strongly influenced by the manufacturing conditions that include the powder preparation procedure and processing conditions such as the sintering temperature, rate of cooling and sintering duration.…”
Section: Introductionmentioning
confidence: 99%
“…This graph shows the relationship between natural logarithm of resistivity and reciprocal temperature 1/T . The plots of all the samples can be described by Arrhenius relationship [19][20][21][22]:…”
Section: Electrical Characteristicsmentioning
confidence: 99%
“…Manganese-based, transition metal, spinel oxide ceramics, with the general formula AB 2 O 4 , have generated much interest as negative temperature coefficient (NTC) thermistors in various domestic and industrial applications owing to their high temperature sensitivity, fast response, convenience in use, and low cost [1][2][3]. In the spinel structure, the oxygen anions are arranged in a cubic close-packed configuration with cations occupying one-eighth of the tetrahedral interstices (A sites) and half of the octahedral interstices (B sites) [4,5].…”
Section: Introductionmentioning
confidence: 99%