The Victoria Land Basin (VLB) has a total width of 140-160 km and extends 95-100 km in N-S. The Terror Rift, composed by the Discovery Graben and the Lee Arch, is a Neogene structure with E-W orthogonal extension and N-S trending faults. Many Cenozoic volcanoes in the southern VLB with a N-S lineation belong to the McMurdo Volcanic Groups. However, due to multiple glaciations and limited seismic data, the volcanic processes are still uncertain in the northern VLB, especially in the Terror Rift. Multi-channel seismic profiles have been collected at the VLB from the 32nd Chinese National Antarctic Research Expedition (CHINARE). We utilize four seismic profiles from the CHINARE and some historical profiles, combined with gravity and magnetic anomalies, to analyze faults and stratigraphic characteristics in the northern Terror Rift and volcanism in the VLB. The negative flower structures found in the northern Terror Rift prove that the Terror Rift is affected by the dextral strike-slip faults from East Antarctica (EANT). After the initial orthogonal tension, the rift turned into the oblique extension, forming a set of normal faults that concave upwards and accommodation zone in the Terror Rift. On Lee Arch, several stages of domino-style normal faults formed and converged to a detachment fault. Under the action of gravity, the strata bend upward and form an overturned anticline. Many deep faults and thin strata subjected to erosions facilitated volcanic activity. A brittle volcanic region in the VLB is affected by the dextral strike-slip movements and E-W extension, resulting in two Cenozoic volcanic chains which connect three igneous provinces in the VLB: the Hallett, Melbourne, and Erebus Province. Chains are composed of mud volcanoes with magnetic cores, volcanic intrusions, and younger volcanic eruptions. Volcanisms have experienced opposite polarity of the geomagnetic field and show negative magnetic anomalies in Antarctica, indicating the occurrence of multiple volcanic activities.