Neptunyl(VI) Nitrate Coordination Polymer with Bis(2-pyrrolidone) Linkers Highlighting Crystallographic Analogy and Solubility Difference in Actinyl(VI) Nitrates

Takeyama, Tomoyuki; März, Juliane; Ono, Ryoma; Tsushima, Satoru; Kohara, T.

doi:10.3390/inorganics11030104

Search citation statements

Order By: Relevance

Paper Sections

Select...

Results1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2023

Publication Types

Select...

Article1

Relationship

Self Cite1

Independent0

Authors

Journals

Cited by 1 publication

(1 citation statement)

References 23 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…[Np IV (tBu-pdiop)(NO 3 ) 2 (py)] was formed in the reaction between Np VI O 2 (NO 3 ) and organic ligands, [4,15,16] the formation of the Np IV complex observed in this study is highly unusual. We were thus interested in identifying the reducing agent responsible for the reduction of Np VI O 2 2 +…”

Section: Resultsmentioning

confidence: 61%

Fate of Oxidation States at Actinide Centers in Redox‐Active Ligand Systems Governed by Energy Levels of 5 f Orbitals

Takeyama,

Tsushima,

Gericke

et al. 2023

Chemistry A European J

Self Cite

View full text Add to dashboard Cite

We report the formation of a NpIV complex from the complexation of NpVIO22+ with the redox‐active ligand tBu‐pdiop2− = 2,6‐bis[N‐(3,5‐di‐tert‐butyl‐2‐hydroxyphenyl)iminomethyl]pyridine. To the best of our knowledge, this is the first example of the direct complexation‐induced chemical reduction of NpVIO22+ to NpIV. In contrast, the complexation of UVIO22+ with tBu‐pdiop2− did not induce the reduction of UVIO22+, not even after the two‐electron electrochemical reduction of [UVIO2(tBu‐pdiop)]. This contrast between the Np and U systems may be ascribed to the decrease of the energy of the 5f orbitals in Np compared to those in U. The present findings indicate that the redox chemistry between UVIO22+ and NpVIO22+ should be clearly differentiated in redox‐active ligand systems.

show abstract

Section: Resultsmentioning

confidence: 61%