Network analysis and percolation transition in hydrogen bonded clusters: nitric acid and water extracted by tributyl phosphate

Abstract

Extraction of polar molecules by amphiphilic species results in a complex variety of clusters whose topologies and energetics control phase behavior and efficiency of liquid-liquid separations. A computational approach including quantum mechanical vibrational frequency calculations and molecular dynamics simulation with intermolecular network theory is used to provide a robust assessment of extractant and polar solute association through hydrogen bonding in the tributyl phosphate (TBP)/HNO/HO/dodecane system for the first time. The distribution of local topologies of the TBP/HNO/HO hydrogen bonded clusters is shown to be consistent with an equilibrium binding model. Mixed TBP/HNO/HO clusters are predicted that have not been previously observable in experiment due to limitations in scattering and spectroscopic resolution. Vibrational frequency calculations are compared with experimental data to validate the experimentally observed TBP-HNO-HNO Chain structure. At high nitric acid and water loading, large hydrogen-bonded clusters of 20 to 80 polar solutes formed. The cluster sizes were found to be exponentially distributed, consistent with a constant average solute association free energy in that size range. Due to the deficit of hydrogen bond donors in the predominantly TBP/HNO organic phase, increased water concentrations lower the association free energy and enable growth of larger cluster sizes. For sufficiently high water concentrations, changes in the cluster size distribution are found to be consistent with the formation of a percolating cluster rather than reverse micelles, as has been commonly assumed for the occurrence of an extractant-rich third phase in metal-free solvent extraction systems. Moreover, the compositions of the large clusters leading to percolation agrees with the 1 : 3 TBP : HNO ratio reported in the experimental literature for TBP/HNO/HO third phases. More generally, the network analysis of cluster formation from atomic level interactions could allow for control of phase behavior in multi-component solutions of species with a variety of hydrogen bond types.

A review of acid recovery from acidic mining waste solutions using solvent extraction

“…HNO 3 is used as a dissolving agent in nuclear, chemical and metallurgical industries . At the present time, all plants for reprocessing spent nuclear fuels use the Plutonium Uranium Redox Extraction (PUREX) process for recovering the uranium and plutonium that are present in these fuels .…”

“…HNO 3 is used as a dissolving agent in nuclear, chemical and metallurgical industries . At the present time, all plants for reprocessing spent nuclear fuels use the Plutonium Uranium Redox Extraction (PUREX) process for recovering the uranium and plutonium that are present in these fuels . HNO 3 is also used in the manufacture of silicon wafer, where chemical etching methods use mixed acids to remove debris generated in the wafer cutting and grinding process of single crystal silicon .…”

“…TBP is a solvating extractant used at industrial scale for the reprocessing of spent nuclear fuel . TBP is generally used for purification of crude uranium, thorium and plutonium from nitric acid medium .…”

“…TBP is a solvating extractant used at industrial scale for the reprocessing of spent nuclear fuel . TBP is generally used for purification of crude uranium, thorium and plutonium from nitric acid medium . The PUREX process is, historically, the most studied solvent extraction system used to recover uranium and plutonium from used nuclear fuel .…”

“…The selection of the optimal technology for acid recovery is complex and no single process fits all scenarios. The optimal solution might reside in the combination of different technologies resulting in a process able to exploit the respective advantages and overcome the weaknesses of each technology . However, this study is focused on solvent extraction for acid recovery.…”