2000
DOI: 10.1016/s0079-6700(00)00028-9
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Network structure formation during crosslinking of organic coating systems

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Cited by 208 publications
(142 citation statements)
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“…Other possibilities such as steric effects on reactivity or intra-molecular loop formation might be operative, but these need a more rigorous treatment that falls out of the scope of this work [29,[54][55][56][57][58]. In addition, reaction of all the epoxy or amine groups might not be possible due to topological restrictions towards the end of the process [23]. Therefore, for simplicity purposes, the network build-up process will be described and analyzed in detail only in the ideal case and deviations from this ideal behaviour will be discussed in the subsequent comparison of the experimental results with the theoretical predictions.…”
Section: Epoxy-amine Crosslinkingmentioning
confidence: 99%
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“…Other possibilities such as steric effects on reactivity or intra-molecular loop formation might be operative, but these need a more rigorous treatment that falls out of the scope of this work [29,[54][55][56][57][58]. In addition, reaction of all the epoxy or amine groups might not be possible due to topological restrictions towards the end of the process [23]. Therefore, for simplicity purposes, the network build-up process will be described and analyzed in detail only in the ideal case and deviations from this ideal behaviour will be discussed in the subsequent comparison of the experimental results with the theoretical predictions.…”
Section: Epoxy-amine Crosslinkingmentioning
confidence: 99%
“…In addition, modification of the amine groups in hyperbranched poly(ethyleneimine)s is commonly reported to be incomplete [47], to a similar extent to that reported in the present work. It is acknowledged a number groups in the hyperbranched structure are less accessible [23] and may be eventually prevented from reacting at all during the crosslinking process due to topological limitations. Table 3 also shows other relevant parameters determined from the calorimetric analysis of the cured samples.…”
Section: Comparison Of Theory With Experimentsmentioning
confidence: 99%
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“…(1) where f aw is second moment of functionality distribution, sometimes called weighted average functionality and is defined as [13] …”
Section: Introductionmentioning
confidence: 99%