In this research, an electronic nose (e-nose) system was used to discriminate the volatile odors produced by banana during shelf-life process. A measurement system, equipped with six metal oxide semiconductor (MOS) sensors, was used to generate a recognition pattern of the volatile compounds of the banana samples. For pattern classification on data obtained from the sensor array of the electronic nose system, back-propagation multilayer perceptron (BP-MLP) neural network was used. By using BP-MLP technique, 97.33 and 94.44% classification successes were achieved for ripening and senescence period of banana respectively. Sensor array ability in classification of shelflife stages using support vector machines (SVM) analysis was investigated which leaded to develop the application of a specific e-nose system by using the most effective sensors or ignoring the redundant sensors. According to the results, it is concluded that the electronic nose could be a useful tool for discriminating between shelf-life stages of banana.