Neutrino Factory R&amp;D in the U.S.

Zisman, Michael S.

doi:10.1063/1.1818377

Cited by 4 publications

(2 citation statements)

References 11 publications

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“…[8][9][10][11][12] Several synthetic routes for preparation of poly͑DMcT͒ have been reported. [8][9][10][11][12]55 The dibasic form of DMcT, Li 2 DMcT•2H 2 O, has also been studied for use as a component in both high-temperature and roomtemperature battery systems. [7][8][9][10]45,48 The methyl derivative of DMcT, McMT, has been studied and used in much the same context as DMcT ͑vide supra͒, especially in that McMT has been shown to coordinate many transition metal centers.…”

Section: Introductionmentioning

confidence: 99%

Organosulfur/Conducting Polymer Composite Cathodes

Pope¹,

Sato²,

Shoji³

et al. 2002

J. Electrochem. Soc.

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The dimercaptan 2,5-dimercapto-1,3,4-thiadiazole ͑DMcT͒ has been employed as a component in secondary lithium battery cathodes. However, spectroscopic studies of its behavior have been impeded by general uncertainty regarding its vibrational band character. The purpose of this study is to provide a spectroscopic basis for the unambiguous determination of protonation and oxidation state of DMcT. The first part of this paper is concerned with structural and spectroscopic assignment of DMcT and some derivatives. Several structural and spectroscopic assignments are intrinsically interesting, including ͑i͒ the suggestion that the thioamide-containing compounds adopt the thione tautomer structure whenever the opposite nitrogen is unsubstituted and ͑ii͒ assignment of an A 1 ring mode for the first time for these compounds. The second part of this paper uses that resource to examine the in situ Raman spectroelectrochemistry of DMcT in a nonaqueous solvent. The results confirm, in part, the redox wave assignments made previously in the literature. Specifically, Raman spectroelectrochemistry of solutions of DMcT and the lithium salt of its first conjugate base ͑LiDMcT͒ show that at ca. 0.8 V LiDMcT is oxidized while DMcT is not oxidized, and that at ϩ1.9 V both species were oxidized. Results regarding oxidation-initiated precipitation of oligomers are also reported.

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Section: Introductionmentioning

confidence: 99%

Organosulfur/Conducting Polymer Composite Cathodes

Pope¹,

Sato²,

Shoji³

et al. 2002

J. Electrochem. Soc.

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“…(The required decisions are discussed in Ref. [23].) In practice, optimizing the design and reducing the number of options require information on relative costs.…”

Section: Issues To Study During the Issmentioning

confidence: 99%