Embrittlement is one of the most important effects affecting reactor pressure vessel (RPV) aging. RPV is irradiated with neutrons and gammas, especially fast neutrons, which mainly lead to embrittlement of RPV during operation lifetime of nuclear reactors. Therefore, the radiation-induced embrittlement of the RPV should be carefully evaluated. In this paper, a preliminary calculation was performed using the MCNP5 code to identify the areas in the RPV of the VVER-1000/V320 reactor where the neutron and gamma fluxes are maximum. Also, the neutron and gamma fluence distributions on the RPV were investigated and evaluated along with their energy spectra. These calculations are the starting point for the evaluation of radiation damage to RPV of VVER reactors.