Neutron Diffraction Study of [K(18-crown-6)] [(PPh3)2ReH6Cr(CO)3], a Bimetallic Donor-Acceptor Complex⋆

Drabnis, Mary H.; Bau, Robert; Mason, Sax A.; Freeman, Jeffrey W.; Ernst, Richard D.

doi:10.1002/(sici)1099-0682(199806)1998:6<851::aid-ejic851>3.0.co;2-1

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Cited by 4 publications

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Activation of Organic Substrates on Multi-Metallic Sites of Transition Metal Polyhydride Clusters Having C5Me5 Groups as Auxiliary Ligands

Suzuki

2002

Eur. J. Inorg. Chem.

106

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An overview of the chemistry of the di‐ and trinuclear transition metal polyhydride complexes containing only C5Me5 groups as auxiliary ligands is presented. The synthesis of a series of η5‐C5Me5 polyhydride clusters and their reactivities centered about some typical examples of “multi‐metallic activation” including the cleavage of carbon−hydrogen bonds of alkanes, carbon‐carbon bond of cyclopentadiene, and carbon−carbon double bond of 1,1‐disubstituted alkenes, achieved on the reaction site of the polyhydride‐bridged clusters, are reported. (© Wiley‐VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)

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Activation of Organic Substrates on Multi-Metallic Sites of Transition Metal Polyhydride Clusters Having C5Me5 Groups as Auxiliary Ligands

Suzuki

2002

Eur. J. Inorg. Chem.

106

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Structure and Bonding in Organometallic Compounds: Diffraction Methods

Brammer

Espallargas

2007

Comprehensive Organometallic Chemistry III

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[{ReH₂(PMePh₂)₂}₂(μ-H)₃]^-: The First Member of a New Class of Anionic Polyhydride Dimers [Re₂H₇L₄]^-

et al. 2001

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[K(Q)][{ReH2(PMePh2)2}2(μ-H)3] is prepared by treatment of {ReH2(PMePh2)2}2(μ-H)4 with potassium hydride and a crown ether (Q = 18-crown-6 or 1,10-diaza-18-crown-6). The [K(1,10 diaza-18-crown-6)]+ salt contains NH ... HRe protonic−hydridic bonds and has been characterized by 31P NMR, variable temperature 1H NMR, IR, and X-ray crystallography. The pK α THF = 33 of {ReH2(PMePh2)2}2(μ-H)4 was determined on the basis of its reaction with [K(2,2,2-crypt)][PO(OEt)2NPh].

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Neutron Diffraction Study of [K(18-crown-6)] [(PPh3)2ReH6Cr(CO)3], a Bimetallic Donor-Acceptor Complex⋆

Cited by 4 publications

References 23 publications

Activation of Organic Substrates on Multi-Metallic Sites of Transition Metal Polyhydride Clusters Having C5Me5 Groups as Auxiliary Ligands

Activation of Organic Substrates on Multi-Metallic Sites of Transition Metal Polyhydride Clusters Having C5Me5 Groups as Auxiliary Ligands

Structure and Bonding in Organometallic Compounds: Diffraction Methods

[{ReH₂(PMePh₂)₂}₂(μ-H)₃]^-: The First Member of a New Class of Anionic Polyhydride Dimers [Re₂H₇L₄]^-

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Neutron Diffraction Study of [K(18-crown-6)] [(PPh3)2ReH6Cr(CO)3], a Bimetallic Donor-Acceptor Complex⋆

Cited by 4 publications

References 23 publications

Activation of Organic Substrates on Multi-Metallic Sites of Transition Metal Polyhydride Clusters Having C5Me5 Groups as Auxiliary Ligands

Activation of Organic Substrates on Multi-Metallic Sites of Transition Metal Polyhydride Clusters Having C5Me5 Groups as Auxiliary Ligands

Structure and Bonding in Organometallic Compounds: Diffraction Methods

[{ReH2(PMePh2)2}2(μ-H)3]-: The First Member of a New Class of Anionic Polyhydride Dimers [Re2H7L4]-

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[{ReH₂(PMePh₂)₂}₂(μ-H)₃]^-: The First Member of a New Class of Anionic Polyhydride Dimers [Re₂H₇L₄]^-