1988
DOI: 10.1016/0001-6160(88)90293-3
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Neutron powder diffraction studies of transition metal hemicarbides M2C1−—II. In situ high temperature study on W2C1− and Mo2C1−

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Cited by 141 publications
(101 citation statements)
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“…The relative stabilities of different carbon positions within the interstitial sites was also investigated. The results confirm the experimentally observed Fe 2 N-ζ structure [59] as the most stable. The bulk modulus and formation energy of Mo 2 C was also evaluated.…”
Section: Resultssupporting
confidence: 90%
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“…The relative stabilities of different carbon positions within the interstitial sites was also investigated. The results confirm the experimentally observed Fe 2 N-ζ structure [59] as the most stable. The bulk modulus and formation energy of Mo 2 C was also evaluated.…”
Section: Resultssupporting
confidence: 90%
“…The bulk lattice constants were determined to be a=4.839 A, b=6.173Å, and c=5.322Å which are within 2.5% of the experimental values (a=4.72, b=6.01, c=5.20) [59]. The relative stabilities of different carbon positions within the interstitial sites was also investigated.…”
Section: Resultsmentioning
confidence: 71%
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“…Re 2 N and Re 2 C having space group P63/mmc (194) [8,10] can only be stable at high temperature-high pressure condition. Both Cr 2 N and beta-Ta 2 N [12,13] show space group of P63/mmc (194) at ambient condition and Fe 2 N and Mo 2 C shows stability in the space group of Pbcn (60) at ambient condition while they are showing p3 − m1(164) symmetry only at high temperature [14]. None of them crystallizes in a space group of P 3 − m1 (164) at ambient condition which opens up to explore the hydrostatic quenching process more extensively.…”
Section: Introductionmentioning
confidence: 99%
“…The sequence of the change in the polymorphic modifications of the carbide W 2 C as a function of temperature that is assumed in handbook [1] is different from that proposed in [3]. Table 1 lists the phases and the characteristics according to the data in [1, 3,[6][7][8][9][10][11][12][13][14]. In [1], the following modifications are indicated for the carbide W 2 C: ordered rhombic phase of type PbO 2 (ξ-Fe 2 N) above 2500°C, disordered hexagonal phase of type L′ 3 within the range 2100°C to 2500°C, and ordered phase of type C6 at 1250-2100°C.…”
Section: Introductionmentioning
confidence: 99%