2024
DOI: 10.1002/ange.202403607
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New Alkalescent Electrolyte Chemistry for Zinc‐Ferricyanide Flow Battery

Liping Zhi,
Chenyi Liao,
Pengcheng Xu
et al.

Abstract: Alkaline zinc‐ferricyanide flow batteries are efficiency and economical as energy storage solutions. However, they suffer from low energy density and short calendar life. The strongly alkaline conditions (3 mol L‐1 OH‐) reduce the solubility of ferri/ferro‐cyanide (normally only 0.4 mol L‐1 at 25 oC) and induce the formation of zinc dendrites at the anode. Here, we report a new zinc‐ferricyanide flow battery based on a mild alkalescent (pH 12) electrolyte. Using a chelating agent to rearrange ferri/ferro‐cyani… Show more

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