“…The PIXE-PIGME procedures (using absolute ppm counts of Ti, Mn, Rb, Sr, Y, Nb, F, Zn, Zr and ratios of Al/Na, F/Na, K/Fe, Ca/Fe, Mn/Fe, Rb/Fe, Sr/Fe, Y/Fe, Zr/Fe, (cf. Bird 1996)) were successfully used in the past to distinguish sources in the Pacific, and of these, Fluorine (F) is particularly important (Bird 1996;Bird et al 1981;Bird et al 1997). Unfortunately, analysing F and Zinc (Zn) with LA-ICP-MS is problematic, because the ionisation potential of F exceeds both that of the carrier gas Argon (Jarvis et al 1992), which means that F can't be effectively ionised (Falkner et al 1995, 412), and of an overlapping of the atomic weight of Zn 64 /Zn 70 with isotopes of Ni 64 and Ge 70 .…”