2020
DOI: 10.3390/foods9101477
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New C-Glycosidic Ellagitannins Formed upon Oak Wood Toasting, Identification and Sensory Evaluation

Abstract: In the courses of studies on ellagitannin changes during oak wood toasting, two C-glycosidic ellagitannins were isolated from the french oak wood for the first time. These two compounds exhibited [M−H]− ion peak at m/z 1055.0631 (compound A) and at m/z 1011.0756 (compound B). A compound is named Castacrenin E and is produced by Castacrenin D oxidation. Castacrenin D is a vescalagin with an additional aromating ring to the C-1 through a C-C bond. These compounds are not only found under laboratory conditions bu… Show more

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Cited by 13 publications
(12 citation statements)
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“…Barrel toasting is probably the most important step in barrel manufacturing, as it influences oak wood chemical composition, which is then likely to migrate into the wine and spirits during ageing, affecting their organoleptic properties. Oak toasting leads to wood compound thermodegradation, which in turn leads to the release of new volatile and non-volatile compounds (Cadahía et al, 2001, Cadahía et al, 2003Chira et al, 2020;Jordão et al, 2006;Mosedale and Puech, 1998). The impact of toasting on the aromatic profile of Portuguese spirits in contact with wood and on whisky has been studied from a physico-chemical point of view (Caldeira et al, 2002;Caldeira et al, 2006).…”
Section: Introductionmentioning
confidence: 99%
“…Barrel toasting is probably the most important step in barrel manufacturing, as it influences oak wood chemical composition, which is then likely to migrate into the wine and spirits during ageing, affecting their organoleptic properties. Oak toasting leads to wood compound thermodegradation, which in turn leads to the release of new volatile and non-volatile compounds (Cadahía et al, 2001, Cadahía et al, 2003Chira et al, 2020;Jordão et al, 2006;Mosedale and Puech, 1998). The impact of toasting on the aromatic profile of Portuguese spirits in contact with wood and on whisky has been studied from a physico-chemical point of view (Caldeira et al, 2002;Caldeira et al, 2006).…”
Section: Introductionmentioning
confidence: 99%
“…In addition, among phenolic compounds, they are the most easily extracted by alcoholic beverages during their maturation. Castalagin and vescalagin are ellagitannins that are most abundant in oak wood, and their content can vary from 40 to 60% of the weight of all ellagitannins [ 20 ]. There are also numerous lyxose/xylose derivatives, such as grandinin and roburin E, as well as dimeric forms, i.e., roburin A, B, C, and D [ 21 ] ( Figure 1 ).…”
Section: Wood In the Production Of Alcoholic Beveragesmentioning
confidence: 99%
“…On the other hand, polysaccharides produce furan compounds, giving the aroma of roasted almonds, nuts, caramel, or bread [ 4 , 5 ]. Chira et al [ 20 ] reported that the intensity of wood toasting may affect the content of ellagitannins and their structure. Depending on the temperature used, these compounds will be more or less degraded.…”
Section: Wood In the Production Of Alcoholic Beveragesmentioning
confidence: 99%
“…More particularly, β-1-O-ethylvescalagin (9) (Figure 2), Toasting is a key step in the barrel manufacturing process. Oak wood toasting leads to thermodegradation of compounds, which release new volatile and non-volatile compounds [15][16][17][18][19]. The toasting applied to the wood varies from one cooperage to another.…”
Section: Introductionmentioning
confidence: 99%