Carbon dioxide (CO2) injection has been widely
used
in conventional reservoirs for enhanced oil recovery and CO2 sequestration. Nevertheless, the effectiveness of CO2 injection in tight reservoirs is limited due to diagenetic processes
that impact displacement efficiency. This research work assesses the
performance of CO2 injection in tight reservoirs and evaluates
oil mobilization and fluid distribution within the rock pore systems.
A set of experiments, including routine core analysis, X-ray diffraction
(XRD), scanning electron microscopy (SEM), and mercury injection capillary
pressure (MICP), was performed on Scioto sandstone. Three core-flooding
runs were conducted to evaluate oil recovery of different injection
schemes, including tertiary miscible CO2 injection, secondary
immiscible CO2 injection, and secondary miscible CO2 injection. A nuclear magnetic resonance (NMR) spectrometer
was utilized to evaluate the fluid distribution in pre- and postflooding
schemes. Results show that secondary miscible CO2 injection
provided the highest displacement efficiency (E
d) of 88%, with oil mobilized from both micro- and macropore
systems, leading to the highest oil recovery of 93% original oil in
place (OOIP). Tertiary miscible CO2 injection had E
d of 67%, providing an ultimate oil recovery
of 79% OOIP mostly from the macropore system. Limited contribution
of micropores during the tertiary miscible CO2 injection
is attributed to the increased water content as a result of previously
conducted secondary water flooding. Secondary immiscible CO2 injection showed the least oil recovery among the injection schemes
of 68% OOIP, which is attributed to the unstable displacement, as
indicated by E
d of 52%. The efficiency
of pore fluid displacement was determined through NMR analyses, and
the findings are in line with the displacement efficiency values obtained
from core-flood experiments, with a strong positive correlation. This
finding is a promising strategy for determining a suitable CO2 injection scheme in tight rocks for oil recovery and CO2 storage.