New crystalline phases of zirconium phosphate possessing ion-exchange properties

Clearfield, Abraham; Blessing, Robert H.; Stynes, James A.

doi:10.1016/0022-1902(68)80224-6

Cited by 232 publications

(86 citation statements)

References 5 publications

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…Table 3 summarizes the results obtained. 44 , the electrostatic interaction with the fixed anion is expected to be considerably reduced for Li + in comparison with Na + and K + .…”

Section: Ion Exchange Reactions and Equilibrium Constantsmentioning

confidence: 99%

The ion exchange properties and equilibrium constants of Li+, Na+ and K+ on zirconium phosphate highly dispersed on a cellulose acetate fibers surface

Borgo¹,

Lazarin²,

Kholin

et al. 2004

J. Braz. Chem. Soc.

View full text Add to dashboard Cite

Fosfato de zircônio altamente disperso foi preparado reagindo acetato de celulose/ZrO 2 (ZrO 2 = 11 wt%, 1,0 mmol g -1 de átomo de zircônio por grama de material) com ácido fosfórico. Highly dispersed zirconium phosphate was prepared by reacting celullose acetate/ZrO 2 (ZrO 2 = 11 wt%, 1.0 mmol g -1 of zirconium atom per gram of the material) with phosphoric acid. High power decoupling magic angle spinning (HPDEC-MAS) 31 P NMR and X-ray photoelectron spectroscopy data indicated that HPO 4 2-is the species present on the membrane surface. The specific concentration of acidic centers, determined by ammonia gas adsorption, is 0.60 mmol g The high values of the separation factors S Na + /Li + and S K + /Li + (up to several hundreds) support the application of this material for the quantitative separation of Na + and K + from Li + from a mixture containing these three ions.

show abstract

“…Table 3 summarizes the results obtained. 44 , the electrostatic interaction with the fixed anion is expected to be considerably reduced for Li + in comparison with Na + and K + .…”

Section: Ion Exchange Reactions and Equilibrium Constantsmentioning

confidence: 99%

The ion exchange properties and equilibrium constants of Li+, Na+ and K+ on zirconium phosphate highly dispersed on a cellulose acetate fibers surface

Borgo¹,

Lazarin²,

Kholin

et al. 2004

J. Braz. Chem. Soc.

View full text Add to dashboard Cite

show abstract

“…Since Clearfield et al 3 synthesized the layered phosphate for the first time in the 1960s, many researchers have investigated for the intercalation chemistry of layered phosphates 1,[4][5][6][7] . For example, they investigated for the intercalation of basic organic compounds such as linear amines (n-alkylamine, α,ω-alkanediamine, and aminoalcohol etc.)…”

Section: Introductionmentioning

confidence: 99%

Intercalation of Biogenic Amines Into Layered Zirconium Phosphates

Hayashi

Yoshikawa

Ryu

et al. 2008

Phosphorus Research Bulletin

View full text Add to dashboard Cite

The biogenic amines (dopamine, serotonin, noradrenaline, and adrenaline) were intercalated into layered zirconium phosphates (ZrP). The intercalation reaction into α-ZrP depended on pH of their aqueous solutions. On the other hand, for γ-ZrP the uptake of dopamine and serotonin increased with the increase of their concentration, where as that of noradrenaline and adrenaline depended on pH. Their intercalation compounds were microscopically investigated by solid-state NMR.

show abstract

“…The existence of several other forms of ZrP has been considered due to the difference on the method of linking the layers together, and due to the amount of hydrated water (Clearfield et al, 1968(Clearfield et al, , 1973. Zirconium atoms lie in planes and form hexagonal arrays within these planes, phosphate groups being situated above and below each zirconium layer.…”

Section: Introductionmentioning

confidence: 99%