New Derivatives of (Carbamoselenoyl)acetic Acid for the Synthesis of Functionally Substituted Selenazoles

Dyachenko, I. V.; Dyachenko, V. D.; Абакаров, Г. М.; Nenajdenko, Valentine G.

doi:10.1134/s1070428021070228

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2024

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Cited by 4 publications

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22.2.5 Selenocarboxylic Acids and Derivatives (Update 2024)

Murai

2024

Knowledge Updates 2024/2

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Selenocarboxylic acids and their derivatives are the selenium isologues of carboxylic, thioic, carbamic, and carbonic acids, and the corresponding esters, amides, and ureas, and are distinguished by the presence of a C=Se bond. The synthesis of these selenium analogues primarily involves incorporating selenium atoms into precursor molecules. This can be achieved by reducing elemental selenium to produce Se2– species, which are then introduced into electrophilic species. Alternatively, carbon nucleophiles can directly bond with elemental selenium, forming carbon–selenium bonds. Compounds containing a P=Se bond, such as Woollins’ reagent, are used to substitute the oxygen in a C=O bond with selenium, creating a C=Se bond. Carbon diselenide (CSe2) is another agent used in synthesizing these derivatives. However, extreme caution is required when handling CSe2 due to its potent odor and toxicity.

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22.2.5 Selenocarboxylic Acids and Derivatives (Update 2024)

Murai

2024

Knowledge Updates 2024/2

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Organic Chemistry in Russian Universities. Achievements of Recent Years

Stoikov,

Antipin,

Burilov

et al. 2024

Russ J Org Chem

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Recent Advances in Design, Synthesis, and Biological Activity Studies of 1,3-Selenazoles

Makhaeva,

Amosova,

Filippov

et al. 2024

Biomolecules

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The review examines recent advances in the design and synthesis of 1,3-selenazole derivatives since 2000. Various synthetic approaches to 1,3-selenazoles and reaction conditions are discussed. The beneficial properties of 1,3-selenazoles, especially their biological activity, are emphasized. Compounds with antitumor, antiviral (HIV-1 and HIV-2), antibacterial, antifungal, antiproliferative, anticonvulsant, and antioxidant activity are highlighted.

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New Derivatives of (Carbamoselenoyl)acetic Acid for the Synthesis of Functionally Substituted Selenazoles

Cited by 4 publications

References 13 publications

22.2.5 Selenocarboxylic Acids and Derivatives (Update 2024)

22.2.5 Selenocarboxylic Acids and Derivatives (Update 2024)

Organic Chemistry in Russian Universities. Achievements of Recent Years

Recent Advances in Design, Synthesis, and Biological Activity Studies of 1,3-Selenazoles

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