As the foundation of quantum secure communication, the quantum key distribution (QKD) network is impossible to construct by using the operation mechanism of traditional networks. In the meantime, most of the existing QKD network routing schemes do not fit some specific quantum key practicality scenarios. Aiming at the special scenario of high concurrency and large differences in application requirements, we propose a new quantum key distribution network routing scheme based on application priority ranking (APR-QKDN). Firstly, the proposed APR-QKDN scheme comprehensively uses the application’s priority, the total amount of key requirements, and the key update rate for prioritizing a large number of concurrent requests. The resource utilization and service efficiency of the network are improved by adjusting the processing order of requests. Secondly, the queuing strategy of the request comprehensively considers the current network resource situation. This means the same key request may adopt different evaluation strategies based on different network resource environments. Finally, the performance of the APR-QKDN routing scheme is compared with the existing schemes through simulation experiments. The results show that the success rate of application key requests of the APR-QKDN routing scheme is improved by at least 5% in the scenario of high concurrency.