2004
DOI: 10.1016/j.apcata.2004.03.010
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New effects during steam gasification of naphthalene: the synergy between CaO and MgO during the catalytic reaction

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Cited by 39 publications
(15 citation statements)
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“…The [W] 4f core level spectrum recorded on samples at 50 and 100 Pa shows the two components associated with 4f 5/2 and 4f 7/2 spin-orbit doublet at 37.5 and 35.4 eV, respectively. These values are in agreement with those found in the literature for [W 6+ ] in stoichiometric films [34][35][36]. However, the spectrum of the sample deposited at 10 Pa have another peak shifted towards lower binding energy, which may be caused by the contribution of [W 5+ ] or [W 4+ ] states resulting from oxygen vacancies in the films [37].…”
Section: Resultssupporting
confidence: 93%
See 1 more Smart Citation
“…The [W] 4f core level spectrum recorded on samples at 50 and 100 Pa shows the two components associated with 4f 5/2 and 4f 7/2 spin-orbit doublet at 37.5 and 35.4 eV, respectively. These values are in agreement with those found in the literature for [W 6+ ] in stoichiometric films [34][35][36]. However, the spectrum of the sample deposited at 10 Pa have another peak shifted towards lower binding energy, which may be caused by the contribution of [W 5+ ] or [W 4+ ] states resulting from oxygen vacancies in the films [37].…”
Section: Resultssupporting
confidence: 93%
“…Fig. 4(a [34,35]. The [W] 4f core level spectrum recorded on samples at 50 and 100 Pa shows the two components associated with 4f 5/2 and 4f 7/2 spin-orbit doublet at 37.5 and 35.4 eV, respectively.…”
Section: Resultsmentioning
confidence: 99%
“…Formates species result from the interaction of adsorbed CO with basic OH-groups of wet and/or hydroxylated surfaces and their formation usually occurs at high temperature [60,64,81,86]. Surface hydroxyl groups come from water vapour which, under ambient air, dissociatively chemisorbs on aluminium oxide surfaces to form adsorbed hydroxyl ions.…”
Section: Comentioning
confidence: 99%
“…Another absorption peaks at 1738 cm −1 assigned to the γ CO carboxylic and aldehyde groups. After heated at 170°C for 1 h, absorption peaks were lower at 1738 cm −1 band and eventually disappeared 20 . The band at 1406 cm −1 indicated the presence of bulk K 2 CO 3.…”
Section: Resultsmentioning
confidence: 96%