New Epoxy Resins Cured with Tetraaminophenyladamantane (TAPA)

Qian, Wei; Lazzeri, Andrea; Cuia, Flavia Di; Scalari, Marco; Galoppini, Elena

doi:10.1002/macp.200400141

Cited by 25 publications

(13 citation statements)

References 20 publications

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“…Adamantane has been incorporated into polymers to increase the hardness and thermal stability of the matrix. Moreover, desirable optical properties, such as low-κ dielectric [95] and high refractive index with low optical dispersion [18], can also be achieved. Compared to other inorganic nanofillers, organic adamantanes show better affinity with organic polymers [96].…”

Section: Adamantane and Its Derivativesmentioning

confidence: 99%

Nanotechnology of diamondoids for the fabrication of nanostructured systems

Yeung

Dong

Chen

et al. 2020

Nanotechnology Reviews

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Diamondoids are cage-like hydrocarbon materials with unique characteristics such as low dielectric constants, negative electron affinity, large steric bulk, and electron-donating ability. They are widely used for advanced functional materials in nanocomposite science. Surface modification of diamondoids also produces functional derivatives that broaden its applications. This article provides a concise review of the fundamentals of diamondoids, including their origin and functionalization, electronic structure, optical properties, and vibrational characteristics. The recent advances of diamondoids and their derivatives in applications, such as nanocomposites and thin film coatings, are presented. The fabrication of diamondoid-based nanostructured devices, including electron emitters, catalyst sensors, and light-emitting diodes, are also reviewed. Finally, the future developments of this unique class of hydrocarbon materials in producing a novel nanostructure system using advanced nanotechnologies are discussed. This review is intended to provide a basic understanding of diamondoid properties, discuss the recent progress of its modifications and functionalization, and highlight its novel applications and future prospects.

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Section: Adamantane and Its Derivativesmentioning

confidence: 99%

Nanotechnology of diamondoids for the fabrication of nanostructured systems

Yeung

Dong

Chen

et al. 2020

Nanotechnology Reviews

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“…104 The resultant cured epoxy molecular composites exhibited superior thermal properties as well as a good dielectric performance at high frequencies. 104 The resultant cured epoxy molecular composites exhibited superior thermal properties as well as a good dielectric performance at high frequencies.…”

Section: Diamondoids In Crosslinking Networkmentioning

confidence: 99%

Derivatization of diamondoids for functional applications

et al. 2015

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Diamondoids, a group of hydrocarbon cage molecules that resemble diamond lattice, are attracting increasing interest in the past decade. Their diamond-like structure warrants that diamondoids inherit the superior properties of diamond at nanoscale, including exceptional hardness and stiffness, high thermal stability, high chemical resistance, unique optical properties and fluorescence, and excellent biocompatibility. To effectively take advantage of the fascinating properties of diamondoids, they must be properly functionalized so that they can be covalently incorporated into the host systems or compatibly mixed with the hosts. Herein, the origin, synthesis, derivatization, and application of diamondoids are reviewed. In particular, how the derivatized diamondoids for various functional applications, including pharmaceuticals, polymers, fine chemicals, nanomaterials, and optical devices, are discussed. It is hoped that this review article can attract more interest in diamondoids, which in turn helps motivate the development of new synthesis and application of diamondoids and their derivatives so that this group of unique molecules can bring more benefits. Scheme 3 Bromination of adamantane under phase-transfer conditions.Scheme 4 Synthesis of 1,3,5,7-tetrabromoadamantane.Scheme 5 Preparation of 1-adamantanol by the ozonation of adamantane over silica gel.Scheme 6 Preparation of adamantyl amine.Scheme 7 Preparation of 1,3-adamantanedicarboxylic acid.

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“…A better way for tetra‐azidation is performed via the formation of tetradiazonium salts generated from the corresponding tetraamine ( 16 ) . The latter is produced from 12 in two easy steps (Scheme ) . Another possibility to create clickable scaffolds is the synthesis of the tetra‐alkyne ( 14 ) through palladium‐catalyzed coupling of the tetraiodine with 2‐methyl‐3‐butyn‐2‐ol or with trimethylsilylacetylene followed by subsequent deprotection.…”

Section: Introductionmentioning

confidence: 99%

Multifunctional adamantane derivatives as new scaffolds for the multipresentation of bioactive peptides

Grillaud

Bianco

2014

Journal of Peptide Science

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The remarkable structural and chemical properties of adamantane afford attractive opportunities to design various adamantane-based scaffolds for biomedical applications. A wide range of mono-functionalized adamantane compounds have already been investigated and reviewed, mostly as anti-viral agents. The four bridgehead positions of adamantane provide many possibilities to design poly-functional derivatives, and the recent conception of adamantane building blocks with multiple substituents has shown promising applications in several domains. In this review, we provide a detailed description of the different ways to synthesize multifunctional derivatives starting from adamantane molecule as the main core. We will then describe the interesting biological activity of the diverse multivalent scaffolds, focusing in particular on peptide-based systems. The results reported here will certainly encourage the development of novel adamantane-based structures for biological purposes.

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New Epoxy Resins Cured with Tetraaminophenyladamantane (TAPA)

Cited by 25 publications

References 20 publications

Nanotechnology of diamondoids for the fabrication of nanostructured systems

Nanotechnology of diamondoids for the fabrication of nanostructured systems

Derivatization of diamondoids for functional applications

Multifunctional adamantane derivatives as new scaffolds for the multipresentation of bioactive peptides

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