Foams
are widely used in the oil and gas industry due to their unique viscous
and elastic properties. However, typical foam injection methods into
reservoirs require large equipment with high injection pressure, which
might not be suitable for development of offshore oilfields, deep
wells, or high condensate petroleum reservoirs. Here, for the first
time, we report self-generated heat foams (SGHFs) that are systematically
generated and studied by combining self-generated nitrogen gas reactants
(sodium nitrite and ammonium chloride) and environmentally friendly
surfactants. Sandpack oil recovery flooding experiments at 60 °C
and 4 MPa along with two-dimensional (2D) visualization micromodel
experiments were carried out to analyze the oil displacement mechanisms.
Various oil recovery aspects such as heat production, oil viscosity
reduction, foam generation, profile control, and heat-foam synergistic
effects were investigated. The results showed that SGHFs can increase
oil recovery by 33.9% from homogeneous (permeability of ∼2
Darcy) single layer formation and by 20.4% from heterogeneous (permeability
ratio >10) multilayer formation. The incremental oil recovery by
SGHFs was much higher than that of conventional foam or self-generated
heat (SGH) without foam. The heat produced by the SGHF chemical reaction
increased the temperature of the crude oil by 13 °C, reduced
the crude oil viscosity by 35%, and helped increase oil recovery by
reducing the mobility ratio. Moreover, the foams generated by SGHFs
had a remarkable effect on the profile (conformance) control in the
presence of crude oil. The synergistic effect between the heat and
the foam produced by SGHF chemical reaction can be explained by (1)
The chemical reaction can produce small and uniform foam, seen by
the 2D micromodel, which can block large pores in porous media and
enhance sweep efficiency and (2) The uniform sweep efficiency due
to the presence of foam can help distribute the heat and make the
temperature rise evenly along the sandpack, which was beneficial to
reduce the crude oil viscosity throughout the entire porous media
and improve oil recovery.