New group IV phthalocyanines

Rafaeloff, R.; Kohl, F. J.; Krueger, Paul C.; Kenney, Malcolm E.

doi:10.1016/0022-1902(66)80426-8

Cited by 19 publications

(11 citation statements)

References 3 publications

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“…The chlorides are replaced by fluoride atoms on treatment with 49% hydrofluoric acid (HF) on a steam bath, and resulted in the formation of SiPcF2. 27,28 Recently, Bender and coworkers synthesized SiPcF2 by refluxing 1 with either cesium fluoride (CsF) in dimethylformamide or with tetrabutylammonium fluoride in dimethyl sulfoxide. 29 These alternate strategies involved relatively safer fluorinating agents compared to HF and resulted in high reaction yields of 100% and 73% respectively.…”

Section: Scheme 2 Synthetic Routes For Obtaining Sipccl2mentioning

confidence: 99%

Silicon phthalocyanines: synthesis and resurgent applications

Mitra

Hartman

2021

Org. Biomol. Chem.

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Section: Scheme 2 Synthetic Routes For Obtaining Sipccl2mentioning

confidence: 99%

Silicon phthalocyanines: synthesis and resurgent applications

Mitra

Hartman

2021

Org. Biomol. Chem.

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“…It was found that the two axial substituents on the central metal atom could be varied over a wide range and several derivatives were thus prepared [18].…”

Section: Synthesismentioning

confidence: 99%

Synthesis of dihydroxy silicon phthalocyanine tetrasulfonic acid and poly-μ-oxo silicon phthalocyanine tetrasulfonic acid

Gürek

Appel

Mikalo

et al. 2001

J. Porphyrins Phthalocyanines

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ABSTRACT:We describe the synthesis of tetrasulfonated silicon phthalocyanine and its oligomer product prepared by metal salt catalyzed polycondensation. The catalytic effect of H 2 O-free CaCl 2 in quinoline is used for the polycondensation of dihydroxy silicon phthalocyanine to the cofacially arrayed oligomer. Spectroscopic characterization and photoelectron spectroscopy data of the prepared compounds are reported. We present the first results on polypyrrole films doped with these substances.

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“…These are insoluble in CC14 . The appearance of the signal due to NH 2 protons at the same positions in the ligand and its complex shows the non-involvement of this group in coordination 13. The conductance measurements (15-20 ohm" 1 cm 2 mol" 1 ) of 10" 3 M solutions reveal their non-electrolytic behaviour.The electronic spectrum of 2-acetylpyridine thiosemicarbazone exhibits a band at ca.…”

mentioning

confidence: 94%

Coordination Compounds of Germanium(IV) Formed with Soft and Hard Donor Atoms: A Look into the Past and Present Work

Singh¹,

Gupta²,

Chaudhary³

et al. 2005

Main Group Metal Chemistry

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An account of approximately hundred germanium and organogermanium derivatives have been included in this review. The unimolar and bimolar substitution products have been characterized by elemental analyses, conductance measurements, molecular weight determinations and spectral studies, viz., IR, 'H NMR, 13 C NMR, U.V. and mass spectra. Thermal stability has been explained on the basis of TGA data.From the analyses of these studies the donor sites of the ligands are located and geometries of the donor environment around the Ge(IV) acceptor centre have been proposed. Based on these studies, trigonal bipyramidal and octahedral geometries have been proposed for the resulting derivatives. The resulting coloured solids are soluble in most of the common organic solvents. These were found to be monomers, as evidenced by their molecular weight determinations. The low values of molar conductance of the resulting metal complexes in anhydrous DMF show them to be non-electrolytes in nature. The spectral data suggested that the ligands act in monofunctional bidentate, bifunctional tridentate and Afunctional tetradentate manners, coordinating through the hard nitrogen and soft sulfur atoms. All such important aspects, including the biological properties about the germanium complexes synthesized in our laboratory as well as other laboratories, are discussed in brief.

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New group IV phthalocyanines

Cited by 19 publications

References 3 publications

Silicon phthalocyanines: synthesis and resurgent applications

Silicon phthalocyanines: synthesis and resurgent applications

Synthesis of dihydroxy silicon phthalocyanine tetrasulfonic acid and poly-μ-oxo silicon phthalocyanine tetrasulfonic acid

Coordination Compounds of Germanium(IV) Formed with Soft and Hard Donor Atoms: A Look into the Past and Present Work

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