New initiators for the ring-opening thermal polymerization of hexachlorocyclotriphosphazene: synthesis of linear poly(dichlorophosphazene) in high yields

Ganapathiappan, S.; Dhathathreyan, K. S.; Krishnamurthy, Sushil

doi:10.1021/ma00173a010

Cited by 21 publications

(7 citation statements)

References 5 publications

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“…67 Further reactions of these cyclopentadienyl derivatives are summarized in Schemes 2-4, 7 and 8. Recently, q6-arene chromium tricarbonyl derivatives of cyclophosphazenes have been reported. Two strategies have been describeda (Scheme 8; Eqns [7], [8]):…”

Section: Macrocycles Linked With Cyclophosphazenesmentioning

confidence: 99%

Coordination and organometallic chemistry of cyclophosphazenes and polyphosphazenes

Chandrasekhar

Thomas

1993

Applied Organom Chemis

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Section: Macrocycles Linked With Cyclophosphazenesmentioning

confidence: 99%

Coordination and organometallic chemistry of cyclophosphazenes and polyphosphazenes

Chandrasekhar

Thomas

1993

Applied Organom Chemis

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“…The yield of reaction was not so good and was normally between 40-60%, which compelled the researchers to use different catalysts, such as AlCl 3 , BCl 3 , and R 3 Si(CHB 11 X 11 ), to enhance the yield. [22][23][24][25][26] Scheme 1 provides general mechanism that is followed in thermal ring-opening polymerization. 27 This process of ring opening can proceed either in vacuum 28 or in high-boiling solvents.…”

Section: Thermal Ring-opening Polymerizationmentioning

confidence: 99%

Synthesis of polyphosphazenes with different side groups and various tactics for drug delivery

et al. 2017

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“…obtain non-cross-linked polymers at ambient temperature to improve the yield but purification of the polymer product was another problem. HCCP monomer should be highly pure because in the presence of small amounts of impurity or moisture, monomers were converted into cross-linked polymer [17][18][19][20][21][22]. Nowadays there are many synthetic routes for preparation of polyphosphazenes that require elevated temperatures.…”

Section: Thermal Ring-opening Polymerizationmentioning

confidence: 99%

Recent Research Progress in the Synthesis of Polyphosphazene and Their Applications

Amin

Wang

et al. 2009

Designed Monomers and Polymers

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Designed Monomers and Polymers provides a forum for the prompt publication of peer-reviewed, English-language papers on all areas of macromolecular design and application. Emphasis will be placed on the macromolecular preparations including the synthesis, characterization and application of monomers. The experimental part should be provided in such detail (including specific observations, precautionary notes, use of new materials, techniques and their possible problems, etc.) that it could be reproduced by any researcher wishing to repeat the work. The subjects of supramolecular science, initiators, macroinitiators for macromolecular design, as well as the kinetics, mechanism and modeling aspects of polymerization, will be included too. This journal will provide an interface between organic and polymer chemistries and aims to bridge the gap between monomer synthesis and the design of new polymers. The subject of monomers may include old monomers but new methods of synthesis. Author(s) must show the evidence for polymerization (including polycondensation, sequential combination, oxidative coupling, radiation, plasma polymerization, etc.) for new monomers. The field of monomers encompasses functional prepolymers of various architecture, such as hyperbranched polymers, telechelic polymers, macromonomers, or dendrimers. In particular, articles on monomers have been scattered over a vast number of journals: there is no polymer journal that covers a specialized subject such as monomers, whereas monomers are the building blocks of polymers. Designed Monomers and Polymers seeks to redress the balance by providing an international forum for addressing the issue of monomers and the art and science of macromolecular design. Issues will contain: review articles of topical areas, full research papers, short research papers, book reviews, conference reports, and conferences of note. Subscription InformationThe price for Volume 12 (2009) is EUR 951/US$ 1398, including postage and handling charges, as well as access to the electronic version. The price of the electronic version only is EUR 856/US$ 1258. Despatch of issues/electronic access will commence only after receipt of correct payment. Subscription orders should be sent to: Brill Academic Publishers, P.O. Box 9000, 2300 PA Leiden, The Netherlands (orders@brill.nl). Publishing OfficeVSP (an imprint of Brill Academic Publishers), P.O. Box 9000, 2300 PA Leiden, The Netherlands. Tel.: (31-71) 535-3500; Fax: (31-71) 531-7532; e-mail: stm@brill.nl; website: www.brill.nl/dmp Submission of a paper for publication implies the transfer of the copyright from the author(s) to the publisher (as far as copyright may be transferable).© 2009 Koninklijke Brill NV (VSP is an imprint of Brill Academic Publishers) All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise without the prior permission from the copyright holder.Typeset by VTEX, Vilniu...

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New initiators for the ring-opening thermal polymerization of hexachlorocyclotriphosphazene: synthesis of linear poly(dichlorophosphazene) in high yields

Cited by 21 publications

References 5 publications

Coordination and organometallic chemistry of cyclophosphazenes and polyphosphazenes

Coordination and organometallic chemistry of cyclophosphazenes and polyphosphazenes

Synthesis of polyphosphazenes with different side groups and various tactics for drug delivery

Recent Research Progress in the Synthesis of Polyphosphazene and Their Applications

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