Natural gas (NG)-fired
power plants are significant greenhouse
gas (GHG) emitters because of their substantial CO
2
release.
To avoid these emissions, precombustion and postcombustion CO
2
capture alongside oxy-fuel combustion were considered in
the literature. However, because of additional energy requirements,
these options generally induce an approximately 7–10% decrease
in net heat-to-power efficiencies regarding regular NG-air-fired stations
without CO
2
capture. To compensate for this declination,
in this study, a simultaneous generation of power and syngas (CO and H
2
) was proposed in an integrated NG-oxygen-fired gas turbine unit
(GTU). Hence, the combustion chamber in the NG-oxygen-fired gas turbine
cycle was replaced by an NG partial oxidation reactor, which converts
it into syngas. The syngas was separated from the working fluid of
the cycle by the condensation of water vapor (steam), and a part of
it was withdrawn from the GTU to be utilized as a chemical feedstock.
A benchmark thermodynamic analysis at the same input–output
conditions and requirements for carbon capture was conducted to compare
the proposed unit with NG-air and NG-oxygen-fired power plants. The
integration effect was shown by increasing the heat-to-power efficiency
from 48 to 54%. With carbon monoxide (CO) as an intermediate, the
author proposed capturing carbon in NG (methane) in liquid formic
acid, which is a good commodity for transportation to a place where
it can be reconverted into CO or H
2
to manufacture various
industrial chemicals. Simple economic considerations show that because
of a substantially higher cost of formic acid than an equivalent power,
CO conversion into formic acid substantiates the integrated approach
as economically attractive.