Communication rates over quantum channels can be boosted by entanglement, via superadditivity phenomena or entanglement assistance. Superadditivity refers to the capacity improvement from entangling inputs across multiple channel uses. Nevertheless, when unlimited entanglement assistance is available, the entanglement between channel uses becomes unnecessary-the entanglementassisted (EA) capacity of a single-sender and single-receiver channel is additive. We generalize the additivity of EA capacity to general multiple-access channels (MACs) for the total communication rate. Furthermore, for optical communication modelled as phase-insensitive bosonic Gaussian MACs, we prove that the optimal total rate is achieved by Gaussian entanglement and therefore can be efficiently evaluated. To benchmark entanglement's advantage, we propose computable outer bounds for the capacity region without entanglement assistance. Finally, we formulate an EA version of minimum entropy conjecture, which leads to the additivity of the capacity region of phaseinsensitive bosonic Gaussian MACs if it is true. The computable limits confirm entanglement's boosts in optical multiple-access communications.