New organocopper reagents prepared utilizing highly reactive copper

Rieke, Reuben D.; Wehmeyer, R. M.; Wu, Tse-Chong; Ebert, Greg W.

doi:10.1016/0040-4020(89)80072-9

Cited by 63 publications

(4 citation statements)

References 35 publications

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“…Those diesters [37,43] were synthesized by the coupling of the respective organozinc ester with 3-methoxycarbonylpropionyl chloride following a procedure of Rieke and co-workers [44,45]. 4-oxoundecandioic acid (27) (32).…”

Section: Tested Compoundsmentioning

confidence: 99%

Inhibition of Escherichia coli porphobilinogen synthase using analogs of postulated intermediates

Jarret

Stauffer

Henz

et al. 2000

Chemistry & Biology

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Section: Tested Compoundsmentioning

confidence: 99%

Inhibition of Escherichia coli porphobilinogen synthase using analogs of postulated intermediates

Jarret

Stauffer

Henz

et al. 2000

Chemistry & Biology

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“…Active Copper. Rieke and Ebert have developed a highly active copper, which allows the direct formation of a wide variety of organocopper reagents from the respective organic halides without utilizing traditional organolithium or Grignard precursors. − This activated copper is formed by reducing under argon an ethereal solution of CuI·PR 3 with an ethereal solution of preformed lithium naphthalenide or biphenylide. The resulting copper is sufficiently reactive to allow direct oxidative addition to alkyl and aryl halides: …”

Section: Introductionmentioning

confidence: 99%

Carboxylation and Esterification of Functionalized Arylcopper Reagents

et al. 2005

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Functionalized arylcopper reagents have been produced in good yields at 25 degrees C from activated copper and the corresponding functionalized aryl iodides without the need of traditional organolithium or Grignard precursors. These organocopper compounds will undergo carboxylation with CO(2) to form the corresponding copper benzoates. In turn, these salts can be acidified to produce the functionalized aryl acids or treated with appropriate alkyl halides in the presence of a dipolar aprotic solvent to generate the corresponding aryl esters. This methodology permits the formation of functionalized organic acids and esters that could not be generated by the carboxylation of organomagnesium compounds.

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“…[9] Aside from the standard approach to many nanoscale materials, more novel approaches have recently shown that Co 9 O 8 and Ni 2 P hollow nanocrystals can be prepared using the nanoscale Kirkendall effect. [10,11] Organometallic complexes have also been used for metal-oxide nanostructure formation, by employing their sensitivity to moisture and the resulting exothermic decomposition. [12] Many of the routes that result in controllable and phase-pure metallic and metal-oxide nanoparticles are limited to metals and oxides due to the nature of the organometallic complex and its coordinative properties.…”

Section: Introductionmentioning

confidence: 99%