We explore the possibility of observing odderon exchange in the pp → ppK þ K − and pp → ppμ þ μ − reactions at the LHC. We consider the central exclusive production (CEP) of the ϕð1020Þ resonance decaying into K þ K − and μ þ μ −. We compare the purely diffractive contribution (odderon-Pomeron fusion) to the photoproduction contribution (photon-Pomeron fusion). The theoretical results are calculated within the tensor-Pomeron and vector-odderon model for soft reactions. We include absorptive corrections at the amplitude level. In order to fix the coupling constants for the photon-Pomeron fusion contribution we discuss the reactions γp → ωp and γp → ϕp including ϕ-ω mixing. We compare our results for these reactions with the available data, especially those from HERA. Our coupling constants for the Pomeronodderon-ϕ vertex are taken from an analysis of the WA102 data for the pp → ppϕ reaction. We show that the odderon-exchange contribution significantly improves the description of the pp azimuthal correlations and the dP t "glueball-filter variable" dependence of ϕ CEP measured by WA102. To describe the lowenergy data more accurately we consider also subleading processes with Reggeized vector-meson exchanges. However, they do not play a significant role at the LHC. We present predictions for two possible types of measurements: at midrapidity and with forward measurement of protons (relevant for ATLAS-ALFA or CMS-TOTEM), and at forward rapidities and without measurement of protons (relevant for LHCb). We discuss the influence of experimental cuts on the integrated cross sections and on various differential distributions. With the corresponding LHC data one should be able to get a decisive answer concerning the presence of an odderon-Pomeron fusion contribution in single ϕ CEP.