New possibilities of harmonic oscillator basis application for calculation of the ground state energy of a Coulomb non-identical three-particle system

Abstract

A new harmonic oscillator (HO) expansion method for calculation of the non-relativistic ground state energy of the Coulomb non-identical three-particle systems is presented. The HO expansion basis with different size parameters in the Jacobi coordinates instead of only one unique oscillator length parameter in the traditional treatment is introduced. This method is applied to calculate the ground state energy of a number of Coulomb three-particle systems for up to 28 excitation HO quanta. The obtained results suggest that the HO basis with different size parameters in the Jacobi coordinates could lead to significant increasing of the rate of convergence for the ground state energy than in the traditional approach.

Two-Parameter Harmonic Oscillator Expansion Method for Calculating Non-Relativistic Ground State Energy of Coulomb Three-Particle Systems with Two Identical Particles

“…In Ref. [3] the method using the oscillator basis with individual parameters for Jacobi coordinates was developed for the non-relativistic calculation of the ground state energy of a Coulomb system consisting of three different particles. For a nonzero number of oscillator quanta it showed much higher accuracy and convergence rate than the calculation with one nonlinear variational parameter.…”