“…With the rapid development of industrialization, the emission of carbon dioxide (CO 2 ), the major component of greenhouse gases, , has been continually increasing, and this issue inevitably poses a serious threat to the environment . Therefore, how to effectively promote the capture and conversion of CO 2 has become the focus of green chemistry in recent years. , Meanwhile, CO 2 is also a ubiquitous, low-cost, and renewable C1 resource, , and the catalytic transformation of CO 2 into high-value fine chemicals can be regarded as a promising strategy to utilize CO 2 . , However, the inherent thermodynamic stability and kinetic inertness hinder the chemical synthesis of CO 2 , because CO 2 is located in the most stable valence state in carbon derivatives. − At present, chemical fixation of CO 2 is limited by the strict reaction conditions, for instance, the sensitive reagent of noncatalytic processes, , high-cost noble metal catalysts and organic ligands, long reaction time, or extremely high pressure .…”