New process for isophoronediamine synthesis

Gillet, J. P.; Kervennal, J.; Pralus, Magali

doi:10.1016/s0167-2991(08)63336-4

Cited by 5 publications

(1 citation statement)

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“…It involves two consecutive reactions through the formation of an azine during a first step, which follows the same scheme as the addition/reduction of ethanol amine (Scheme ). It has to be noted that azine formation can be considered as a new route to primary amines from ketones …”

Section: Introductionmentioning

confidence: 99%

Biobased Amines: From Synthesis to Polymers; Present and Future

et al. 2016

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Amines are key intermediates in the chemical industry due to their nucleophilic characteristic which confers a high reactivity to them. Thus, they are key monomers for the synthesis of polyamides, polyureas, polyepoxydes, which are all of growing interest in automotive, aerospace, building, or health applications. Despite a growing interest for biobased monomers and polymers, and particularly polyamides, it should be noticed that very few natural amines are available. Actually, there is only chitosan and poly(lysine). In this review we present both fundamental and applied research on the synthesis of biobased primary and secondary amines with current available biobased resources. Their use is described as a building block for material chemistry. Hence, we first recall some background on the synthesis of amines, including the reactivity of amines. Second we focus on the synthesis of biobased amines from all sorts of biomass, from carbohydrate, terpenes, or oleochemical sources. Third, because they need optimization and technological developments, we discuss some examples of their use for the creation of biobased polymers. We conclude with the future of the synthesis of biobased amines and their use in different applications.

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Section: Introductionmentioning

confidence: 99%

Biobased Amines: From Synthesis to Polymers; Present and Future

et al. 2016

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The Development of Industrial Heterogeneous Catalysis

Dingerdissen

Martin

Herein

et al. 2008

Handbook of Heterogeneous Catalysis

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The sections in this article are Introduction The Raw Materials Situation Inorganic Base Chemicals Petroleum Refining Coal and Natural Gas Processing The Base Chemicals Olefins and Aromatics Alcohols, Ethers, Aldehydes, and Ketones Alcohols Methanol Ethanol 2‐Propanol Ethers Aldehydes Acids, Esters, Anhydrides, and Epoxides Acids, Esters, Anhydrides Acetic Acid Epoxides Halogenated Chemicals The Fine Chemicals Catalytic Hydrogenation Hydrogenation of Carbon–Carbon Multiple Bonds Hydrogenation of Carbon–Oxygen and Carbon–Nitrogen Multiple Bonds Reductive Amination Nitrile Hydrogenation Hydrogenation of Nitro Groups Catalysis on Solid Acids and Bases Aromatic Substitution (Friedel–Crafts Alkylation and Acylation) Amination Rearrangement, Isomerization Oxidation Catalysis Oxidation of Alcohols and Aldehydes Epoxidation and Aromatic Ring Hydroxylation Environmental Catalysis Cleaning of Automobile Emissions Removal of Harmful Emissions from Stationary Sources Wastewater Treatment Fuel Cell Catalysis Photocatalytic Applications

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Hydrogenolysis

Smith

1999

Heterogeneous Catalysis in Organic Chemistry

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New process for isophoronediamine synthesis

Cited by 5 publications

References 0 publications

Biobased Amines: From Synthesis to Polymers; Present and Future

Biobased Amines: From Synthesis to Polymers; Present and Future

The Development of Industrial Heterogeneous Catalysis

Hydrogenolysis

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