2016
DOI: 10.4236/ajps.2016.711148
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New Reported Flavonol Characterized by NMR from the Petals of <i>Talipariti elatum S. w.</i> in Cuba

Abstract: From yellow petals of Blue Mahoe, besides the known flavonoids gossypetin and gossypitrin, a new one gossypetin derivative was isolated from ethanolic extracts after Soxhlet extraction. Hence, in this study, we present a validated, sensitive and reliable NMR method for the simultaneous identification of flavonoids in this flower drug. Structure analyses of this flavonoid, revealed the identical glycoside moiety attached to a flavonol skeleton like gossypitrin, for which the structure of gossypetin-3'-O-β-gluco… Show more

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Cited by 6 publications
(6 citation statements)
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“…2 shows the total chromatographic profile of the investigated extract by LC-MS. The LC conditions permitted a good separation of these compounds and were optimized for further separations of crude plant extracts containing aglycones or glycosylated flavonoids were previously identified by our research team [3,4,6].…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…2 shows the total chromatographic profile of the investigated extract by LC-MS. The LC conditions permitted a good separation of these compounds and were optimized for further separations of crude plant extracts containing aglycones or glycosylated flavonoids were previously identified by our research team [3,4,6].…”
Section: Resultsmentioning
confidence: 99%
“…Until now, only gossypitrin (gossypetin-7-O-β-D-glucoside), gossypetin-3'-O-glucoside and quercetin-3-O-glucoside (Isoquercitrin) have been reported from ethanolic extracts of the petals of the flowers in this plant [3][4][5].…”
Section: Introductionmentioning
confidence: 99%
“…The structural determination of the compounds was achieved by mass spectroscopy (MS; Agilent G6550A Q-TOF mass spectrometer and Waters LCT Premier XE UPLC/MS-TOF spectrometer) and nuclear magnetic resonance ( 1 H and 13 C NMR; Bruker Ascend spectrometer) techniques. Totally 3 compounds were isolated from active fraction and the isolates were identified medicarpin-3-O-glucoside (a pterocarpan glycoside), gossypetin-3-O-glucoside (a flavonol glycoside) and naringenin-7-O-glucoside (prunin; a flavanone glycoside) by comparing their spectroscopic data with related literatures [35][36][37].…”
Section: Determination Of the Structure Of Compoundsmentioning
confidence: 99%
“…Gossypetin-3'-O-glucoside was isolated for the first time from the flowers of the plant in Martinica Island by maceration with methanol (24 h), and Soxhlet extraction with methanol, ethyl acetate and 1,2-dimethoxyethane as solvents as discussed in [2] [3]. The last mentioned compound was identified by Cuban and Martinicans researcher in 2016 using UV, IR, HPLC-MS and NMR spectroscopy after its isolation and purification from ethanolic extracts at 95% by Soxhlet extraction of the red petals of the flowers as referred in [4]. Figure 1 shows the macromorphological characteristics of the fruits.…”
Section: Introductionmentioning
confidence: 99%