We study coefficients b n , expressible as sums over the Li/Keiper constants l j , that contain information on the Riemann xi function. We present a number of relations for and representations of b n . These include the expression of b n as a sum over non-trivial zeroes of the Riemann zeta function, as well as integral representations. Conditional on the Riemann hypothesis, we provide the asymptotic form of b n ∼ 2 −n−2 ln n.