New silica based polymeric systems designed for the solid–liquid extraction of uranyl ions

Caprasse, F.; Leroy, D.; Martinot, L.; Lambert, Stéphanie D.; Pirard, Jean‐Paul; Guillaume, J. L.; Jérôme, Christine; Jérôme, Robert

doi:10.1039/b107557h

Cited by 9 publications

(1 citation statement)

References 5 publications

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“…593 There are also a number of reports of the imprinting of metal ions in sol-gel matrices. 189,190,213,232,235,240,241,261,282,289,290 Metal ion-mediated imprinting. Metal ions have the ability to bind to a wide range of functional groups through the donation of electrons from the heteroatoms of ligands to the unfilled orbitals of the outer coordination sphere of the metal.…”

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confidence: 99%

Molecular imprinting science and technology: a survey of the literature for the years up to and including 2003

Andersson²,

et al. 2006

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Over 1450 references to original papers, reviews and monographs have herein been collected to document the development of molecular imprinting science and technology from the serendipitous discovery of Polyakov in 1931 to recent attempts to implement and understand the principles underlying the technique and its use in a range of application areas. In the presentation of the assembled references, a section presenting reviews and monographs covering the area is followed by papers dealing with fundamental aspects of molecular imprinting and the development of novel polymer formats. Thereafter, literature describing attempts to apply these polymeric materials to a range of application areas is presented.

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confidence: 99%

Molecular imprinting science and technology: a survey of the literature for the years up to and including 2003

Andersson²,

et al. 2006

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Synthesis of Bio‐Based Silane Coupling Agents by the Modification of Eugenol

et al. 2021

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A simple method for the synthesis of new bio-based silane coupling agents (SCAs) with a terpene aromatic core by the functionalization of cheap, natural eugenol and its sulfur derivatives using the hydrosilylation of the C=C bonds with HSi(OEt) 3 , followed by nucleophilic substitution reactions of OH/SH groups is presented. The obtained alkoxysilanes possess different polymerreactive functionalities (alkenyl, epoxide, thiirane, thiocarbamoyl, thioester, thioether moieties). This new group of biogenic SCAs was fully characterized using 1 H, 13 C, 29 Si NMR, FT-IR, GC-MS, and HRMS or elemental analysis. Examples of their application as additives to tire rubbers and their influence on several factors are also discussed.

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Selective solid–liquid extraction of cations using solid‐phase polyamides with crown ether moieties as cation host units

Carpintero

Serna

García

et al. 2007

J of Applied Polymer Sci

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This work describes the interaction of alkaline, alkaline earth, transition metal, heavy metal, and lanthanide cations from nitrate solutions with synthetic polyamides. The polyamides have pendant structures acting as cation host moieties. The host subgroups are benzo-12-crown-4, benzo-15-crown-5, benzo-18-crown-6, and the three dipodal counterparts of the three benzo-crown units. This interaction has been analyzed in terms of competitive polyamide solid-phase extraction of nitrate cations from aqueous or acetronitrile solutions. The solid-phase extraction of water or acetonitrile solutions of alkaline, alkaline earth, transition metal, heavy metal, and lanthanide ions using solid-phase polyamides is performed with a degree of selectivity. Higher selectivity is observable in the extraction of Pb(II) from a set of heavy metal ions in water and acetonitrile solutions, and the extraction of Cr(III) from a set of transition metals in acetonitrile solutions. It is a noteworthy result, which along with the reusability of the solid-phase polyamides points to potentially successful applications in the field of environmental chemistry: the decontamination and elimination of poisoning cations, the separation and modification of cation mixtures, and the development of fixed-site carrier membranes for selective transport or manufacture of cationsensitive sensors.

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New silica based polymeric systems designed for the solid–liquid extraction of uranyl ions

Cited by 9 publications

References 5 publications

Molecular imprinting science and technology: a survey of the literature for the years up to and including 2003

Molecular imprinting science and technology: a survey of the literature for the years up to and including 2003

Synthesis of Bio‐Based Silane Coupling Agents by the Modification of Eugenol

Selective solid–liquid extraction of cations using solid‐phase polyamides with crown ether moieties as cation host units

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