1997
DOI: 10.1016/s0379-6779(97)81082-x
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New transparent, colorless, metallically conductive polymer films and their electrochemical transformations

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Cited by 23 publications
(21 citation statements)
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“…One of the solutions to overcome these problems is to use polymer composites, and these nanocomposite materials often lead to multifunctional characteristics exceeding those of their component parts 39–48. In particular, metastable conformations or electronic states such as the mixed‐valence states can be fixed and express curious properties by the assistance of the polymer matrices in the composite materials 42–45.…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…One of the solutions to overcome these problems is to use polymer composites, and these nanocomposite materials often lead to multifunctional characteristics exceeding those of their component parts 39–48. In particular, metastable conformations or electronic states such as the mixed‐valence states can be fixed and express curious properties by the assistance of the polymer matrices in the composite materials 42–45.…”
Section: Introductionmentioning
confidence: 99%
“…In particular, metastable conformations or electronic states such as the mixed‐valence states can be fixed and express curious properties by the assistance of the polymer matrices in the composite materials 42–45. Indeed, the TTF‐containing composite materials were applied in various manners such as a transparent conductive material without significant loss of the conductivity 46–48. Therefore, the formation and distribution of the self‐assemble structure of the nanofillers in the polymer matrices according to the preprogrammed design have great importance to create high‐performance nanocomposite materials.…”
Section: Introductionmentioning
confidence: 99%
“…The X‐ray diffraction data were collected from BL film samples with the same area at identical scan rates. The powder X‐ray diffraction data presented in Figures 2 and S2 show the presence of only 00 l reflections that correspond to the α‐(BEDT‐TTF) 2 I 3 conductor, which indicates that conductive covering layers are formed exclusively from c *‐oriented α‐(BEDT‐TTF) 2 I 3 crystallites regardless of the iodine/solvent annealing temperature 5,9d,15,10b. In this orientation, the molecular conducting ab plane of the α‐(BEDT‐TTF) 2 I 3 crystallites is parallel to the film plane.…”
Section: Resultsmentioning
confidence: 99%
“…Although the XPS measurements give only a semiquantitative elemental composition, the presence of C, O, S, P and W in the film is confirmed. The results show the peaks cor- (Tracz et al, 1997;Peng et al, 1998) occurring of charge transfer from donor to acceptor in the film. The result further confirms that the thin film of charge-transfer salt is indeed formed by using electrochemical process.…”
Section: Photoelectron Spectroscopymentioning
confidence: 91%
“…charge-transfer salts (CT) Triki et al, 1991Triki et al, , 1993Gómez-García et al, 1994Davidson et al, 1989; The main techniques used for the preparation of thin film of charge-transfer salts are Langmuir-Blodgett (Li et al, 2001;Berzina et al, 1993;Kawabata et al, 1990;Troitsky et al, 1992), high vacuum evaporation (Molas et al, 2000;Moldenhauer et al, 1995;Deutsch et al, 1999), reticulate polymer matrix approach, and electrochemical process (Wang et al, 2002). The reported thin films are, however, based largely on the system from ET with highly volatile halogen constituents such as ET/I 2 , while that based on other systems are relatively rare (Wang et al, 2002;Ulanski et al, 1998;Tracz et al, 1997).…”
Section: Introductionmentioning
confidence: 99%