New two-dimensional metal–organic frameworks constructed from 1H-benzimidazole-5,6-dicarboxylic acid with luminescent studies

Wang, Wei; Sun, J.; Zhang, Daojun; Song, Tianyou; Song, Wei; Zhang, Liying; Chen, Yanli; Ye, Fan; Zhang, Ping

doi:10.1016/j.ica.2011.11.044

Cited by 10 publications

(1 citation statement)

References 57 publications

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“…In recent years, the interest in crystalline layered materials has been increasing because their 2D character provides them with extraordinary physicochemical properties [24] such as sizeand shape-dependent electronic and optical properties [25], mechanical strength [25], high surface areas [25], and excellent heat conduction [26]. As a consequence, 2D materials are employed in a vast range of applications in fields such as sensing [27], catalysis [27], molecular recognition [28], energy storage [27,29], (opto)electronics [30] and gas separation [31,32].…”

Section: Introductionmentioning

confidence: 99%

A new zeolitic hydroxymethylimidazolate material and its use in mixed matrix membranes based on 6FDA-DAM for gas separation

Perea-Cachero

Sánchez‐Laínez

Berenguer-Murcia

et al. 2017

Journal of Membrane Science

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The new ZIF named UZAR-S13 is formed by Zn 2+ and 4(5)-(hydroxymethyl)imidazolate. UZAR-S13 has two distinct phases according to SEM and XRD: amorphous spheres and sheet crystals. UZAR-S13 and byproducts, with no N 2 adsorption, rendered a notable CO 2 uptake (up to 3.8 mmol g-1 at 30 bar and 0 °C), approaching values of known ZIFs. The most promising materials were included as fillers in mixed matrix membranes based on copolyimide 6FDA-DAM to study the separation of CO 2 /CH 4 , CO 2 /N 2 , H 2 /CO 2 and H 2 /CH 4. The pore blocking hindered the gas flow of bulky molecules (CH 4 , N 2 and CO 2). The high CO 2 adsorption on sheet crystals also contributed to the decrease in the permeability of CH 4 , N 2 and CO 2 , giving poor selectivities. In contrast, the MMMs improved both the H 2 /CH 4 selectivity (8.9-12.7 vs. 7.2) and permeability of H 2 (544-597 vs. 505 Barrer) of the bare 6FDA-DAM membrane. This emphasizes the potential application of the fillers in the separation by molecular sieving of gas mixtures without CO 2 .

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Section: Introductionmentioning

confidence: 99%

A new zeolitic hydroxymethylimidazolate material and its use in mixed matrix membranes based on 6FDA-DAM for gas separation

Perea-Cachero

Sánchez‐Laínez

Berenguer-Murcia

et al. 2017

Journal of Membrane Science

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Two novel d¹⁰ transition metal complexes based on 1H‐benzimidazole‐5,6‐dicarboxylic acid: Synthesis, structure and multifunctional luminescence detection

Liu

Xing

Zhou

et al. 2019

Applied Organom Chemis

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Two new coordination complexes based on benzimidazole dicarboxylic acid, Zn(Hbidc)⋅H2O (1) and Cd(Hbidc)(H2O) (2), have been synthesized under hydrothermal conditions. The complexes were characterized using elemental analysis, infrared and UV–visible spectroscopies, powder X‐ray diffraction, thermogravimetry and single‐crystal X‐ray diffraction. Structural analyses showed that the crystal structures of 1 and 2 are different, due to the various modes of linking of the benzimidazole dicarboxylic acid. Complex 1 has a two‐dimensional network structure and 2 has a three‐dimensional network structure. In addition, we studied the performance of the fluorescence response of two complexes. Results showed that the complexes can be used as chemical sensors for multifunctional testing, such as for UO22+, xanthine and Fe3+ ions. Even if the concentration is very low, they could also be detected, showing that coordination complexes 1 and 2 have very high fluorescence sensitivity. The detection limit for UO22+ is 5.42 nM (1) and 0.02 nM (2), that for xanthine is 1.37 nM (1) and 0.28 nM (2), and that for Fe3+ ions is 0.76 nM (1) and 0.62 nM (2).

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Mn‐Based Two Dimensional Metal‐Organic Framework Material from Benzimidazole‐5,6‐dicarboxylic Acid

Zhang

Tan

et al. 2016

Chin. J. Chem.

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A new two-dimensional metal-organic framework (MOF) structure has been synthesized by mild solvothermal reaction of MnCl 2 •4H 2 O with 1H-benzimidazole-5,6-dicarboxylic acid (H 3 bidc) at 85 ℃. The structure has been characterized by single-crystal X-ray diffraction, powder X-ray diffraction (PXRD), infrared spectroscopy (FT-IR), and thermogravimetric analysis (TGA). Single-crystal X-ray diffraction analysis revealed that this MOF is a five-coordinated Mn(II) compound exhibiting a layered 2D network, in which the hydrogen-bonding interactions between uncoordinated carboxylic oxygen atoms and N-H groups in the imidazole rings play a key role in the final 3D supramolecular architecture. This MOF shows high thermal stability up to 400 ℃. Furthermore, XRD pattern of the MOF structure was retained for up to 20 d after soaked in water, and only 2.8 wt% of the MOF was decomposed within the first 48 h in water.

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New two-dimensional metal–organic frameworks constructed from 1H-benzimidazole-5,6-dicarboxylic acid with luminescent studies

Cited by 10 publications

References 57 publications

A new zeolitic hydroxymethylimidazolate material and its use in mixed matrix membranes based on 6FDA-DAM for gas separation

A new zeolitic hydroxymethylimidazolate material and its use in mixed matrix membranes based on 6FDA-DAM for gas separation

Two novel d¹⁰ transition metal complexes based on 1H‐benzimidazole‐5,6‐dicarboxylic acid: Synthesis, structure and multifunctional luminescence detection

Mn‐Based Two Dimensional Metal‐Organic Framework Material from Benzimidazole‐5,6‐dicarboxylic Acid

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New two-dimensional metal–organic frameworks constructed from 1H-benzimidazole-5,6-dicarboxylic acid with luminescent studies

Cited by 10 publications

References 57 publications

A new zeolitic hydroxymethylimidazolate material and its use in mixed matrix membranes based on 6FDA-DAM for gas separation

A new zeolitic hydroxymethylimidazolate material and its use in mixed matrix membranes based on 6FDA-DAM for gas separation

Two novel d10 transition metal complexes based on 1H‐benzimidazole‐5,6‐dicarboxylic acid: Synthesis, structure and multifunctional luminescence detection

Mn‐Based Two Dimensional Metal‐Organic Framework Material from Benzimidazole‐5,6‐dicarboxylic Acid

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Two novel d¹⁰ transition metal complexes based on 1H‐benzimidazole‐5,6‐dicarboxylic acid: Synthesis, structure and multifunctional luminescence detection