New type of epoxy resin impregnated graphite electrode for anodic stripping voltammetry

Sykut, K.; Cukrowski, Ignacy; Cukrowska, Ewa

doi:10.1016/s0022-0728(80)80502-x

Cited by 20 publications

(4 citation statements)

References 5 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Typically, these materials are fabricated by suspending a powdered conductor in a polymeric matrix, analogous to the formation of the popular carbon paste (composite) electrode (1), and have included composites fabricated from various epoxies and graphite (2), Teflon and graphite (3), polyethylene and carbon black (4), silicone rubber and graphite (5), Kel-F and graphite (6), and Kel-F and silver (7). Alternatively, a porous conductor can be impregnated with an insulating polymer, and this approach has produced the wax- (8), the styrene- (9) and the epoxy-resin-impregnated (10) graphite electrodes as well as the epoxy-impregnated reticulated vitreous carbon electrode (11).…”

mentioning

confidence: 99%

On the nature of poly(chlorotrifluoroethylene) composite electrode surfaces

Petersen¹,

Weisshaar²,

Tallman³

et al. 1988

Anal. Chem.

View full text Add to dashboard Cite

mentioning

confidence: 99%

On the nature of poly(chlorotrifluoroethylene) composite electrode surfaces

Petersen¹,

Weisshaar²,

Tallman³

et al. 1988

Anal. Chem.

View full text Add to dashboard Cite

“…All experiments were carried out in a three-electrode system using an epoxy-resinimpregnated graphite electrode (IGE) coated with gold as the working electrode, Pt as the auxiliary electrode, and Ag/AgCl as the reference electrode. The IGE (1.2 mm diameter) was prepared from spectrographically pure graphite (Topolcany, Czech) by impregnation as described earlier (12,13). A schematic diagram of the apparatus used for volatilization and accumulation of mercury is shown in Fig.…”

Section: Apparatusmentioning

confidence: 99%

Application of Cold Vapor Differential Pulse Voltammetric Method for Determination of Mercury in Urine Samples

Korolczuk

1997

Microchemical Journal

View full text Add to dashboard Cite

“…A graphite electrode, impregnated with epoxy resin and coated with a mercury film in situ, was used as a working electrode having a working area of 12.5 mm 2. The details of the preparation of this electrode have been described by Sykut et al [15].…”

Section: Apparatusmentioning

confidence: 99%

Silica gel modified with Eriochrome Blue SE as a sorbent in trace analysis for metal ions

Kocjan

Świeboda

1996

Mikrochim Acta

View full text Add to dashboard Cite

Abstract. The sorption of 14 metal ions on silica gel impregnated with a mixture of Aliquat 336 and Eriochrome Blue SE was investigated. It was found that the sorption behaviour depends upon the species and the pH of the loading solution. Alkali metal ions were not retained under any of the investigated conditions. The retained metal ions can be eluted with dilute solutions of hydrochloric or perchloric acid without significant elution of the chelating reagent from the sorbent. The sorbent was used for the separation of metal ion mixtures by column-extraction chromatography and for additional purification of some salt solutions from trace amounts of Zn, Cd, Pb and Cu. The effectiveness of purification was confirmed by anodic stripping voltammetry.Key words: Eriochrome Blue SE, chelating sorbent, extraction chromatography, purification of alkali metal salts.The determination of trace elements often requires their preconcentration and separation from a matrix of macroamounts of other metals [1]. Selective precolumns have been used for on-line concentration with selective elution of interfering matrix components [2]. Column switching, reinjection and suppressor techniques have been employed for the separation and matrix elimination of metals [3]. In the trace analysis of metal ions an iraportant role is played by solid and liquid ion exchangers and their derivatives-the so-called chelating sorbents. Many examples of such sorbents and their applications can be found in the monographs by Myasoedowa and Savvin [4], Mizuike [5] and Braun and Ghersini [6].Chelating sorbents can be obtained in a very simple manner by the impregnation of silica gel with water-insoluble ion-pairs composed of a cation of liquid anionexchanger-Aliquat 336 (methyltricapryl.ammonium chloride) and an anion of a sulfonated chelating reagent [7-1, since it was found that many such reagents are very strongly extracted into solutions of liquid anion-exchangers in organic solvents [8].

show abstract

New type of epoxy resin impregnated graphite electrode for anodic stripping voltammetry

Cited by 20 publications

References 5 publications

On the nature of poly(chlorotrifluoroethylene) composite electrode surfaces

On the nature of poly(chlorotrifluoroethylene) composite electrode surfaces

Application of Cold Vapor Differential Pulse Voltammetric Method for Determination of Mercury in Urine Samples

Silica gel modified with Eriochrome Blue SE as a sorbent in trace analysis for metal ions

Contact Info

Product

Resources

About