Visible-light absorption is a critical factor for photocatalyst activity and absorption of electromagnetic (EM) interference application. The band gap of Fe 2 O 3 is 2 eV, which can be increased by doping with a high-band-gap material such as carbon from activated carbon (AC) with a band gap of 4.5 eV for increased visible-light absorption. The porosity decreases from 88 to 81.6%, and the band gap increases from 2.14 to 2.64 eV by increasing the AC from 10 to 25%, respectively. The photocatalytic activity takes 120 min to produce a harmless product for 10− 20% AC, but 25% AC shows 89.5% degradation in only 90 min and the potential to attenuate the EM wave up to 99% due to the RL being below −20 dB. The secondand third-cycle degradation achieved by the composite Fe 2 O 3 −AC having 25% AC is 88.2 and 86.5% in 90 min, respectively. The pore of the surface state of AC contains a trapped charge, and interaction occurs between the charge (electron/hole) and O 2 or H 2 O to produce OH and superoxide (O 2 − ) radicals. These radicals move inside the molecule of the pollutant (methylene blue (MB)) to break up the bond, with the final products being H 2 O and CO 2 . The X-ray photoelectron (XPS) spectra show that oxygen plays a key role in the interatomic bonding with Fe, C, and MB atoms. The best absorption of EM interference is −21.43 dB, with degradation reaching 89.51% in only 90 min for 25% AC due to its higher band gap and anisotropy constant. Fe 2 O 3 −carbon is a multifunctional material for the green environment because of its electromagnetic interference absorption and photodegradation of wastewater.