“…The polymeric transition from para-wollastonite (β-CaSiO 3 ) to pseudo-wollastonite (α-CaSiO 3 ) occurs when temperature is above 1125 • C [1]. Wollastonite glass-ceramics possess outstanding characteristics, i.e., high whiteness, low moisture absorption, low thermal expansion, low shrinkage, and low dielectric constant, which are suitable for wide applications in ceramics, chemicals, electronic devices, dental implant, construction, and polymers [2][3][4][5].…”